Bis(3-aza­niumylprop­yl)aza­nium hexa­chlorido­bis­muthate(III) monohydrate

The asymmetric unit of the title compound, (C(6)H(20)N(3))[BiCl(6)]·H(2)O, consists of a triprotonated bis­(3-aza­niumylprop­yl)aza­nium cation, two halves of an octahedral [BiCl(6)](3−) anion, each of the Bi(III) atoms lying on an inversion centre, and a water mol­ecule. In the crystal, the anions...

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Detalles Bibliográficos
Autores principales: Elfaleh, Nizar, Chouaib, Hassen, Kamoun, Slaheddine
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2013
Materias:
Metal-Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3884999/
https://www.ncbi.nlm.nih.gov/pubmed/24454174
http://dx.doi.org/10.1107/S1600536813030900
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author Elfaleh, Nizar
Chouaib, Hassen
Kamoun, Slaheddine
author_facet Elfaleh, Nizar
Chouaib, Hassen
Kamoun, Slaheddine
author_sort Elfaleh, Nizar
collection PubMed
description The asymmetric unit of the title compound, (C(6)H(20)N(3))[BiCl(6)]·H(2)O, consists of a triprotonated bis­(3-aza­niumylprop­yl)aza­nium cation, two halves of an octahedral [BiCl(6)](3−) anion, each of the Bi(III) atoms lying on an inversion centre, and a water mol­ecule. In the crystal, the anions and water mol­ecules are linked by O—H⋯Cl hydrogen bonds, forming chains running parallel to [0-11]. The anionic chains and the cations are further linked into a three-dimensional network by N—H⋯Cl and N—H⋯O hydrogen-bond inter­actions.
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spelling pubmed-38849992014-01-17 Bis(3-aza­niumylprop­yl)aza­nium hexa­chlorido­bis­muthate(III) monohydrate Elfaleh, Nizar Chouaib, Hassen Kamoun, Slaheddine Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers The asymmetric unit of the title compound, (C(6)H(20)N(3))[BiCl(6)]·H(2)O, consists of a triprotonated bis­(3-aza­niumylprop­yl)aza­nium cation, two halves of an octahedral [BiCl(6)](3−) anion, each of the Bi(III) atoms lying on an inversion centre, and a water mol­ecule. In the crystal, the anions and water mol­ecules are linked by O—H⋯Cl hydrogen bonds, forming chains running parallel to [0-11]. The anionic chains and the cations are further linked into a three-dimensional network by N—H⋯Cl and N—H⋯O hydrogen-bond inter­actions. International Union of Crystallography 2013-11-16 /pmc/articles/PMC3884999/ /pubmed/24454174 http://dx.doi.org/10.1107/S1600536813030900 Text en © Elfaleh et al. 2013 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Metal-Organic Papers
Elfaleh, Nizar
Chouaib, Hassen
Kamoun, Slaheddine
Bis(3-aza­niumylprop­yl)aza­nium hexa­chlorido­bis­muthate(III) monohydrate
title Bis(3-aza­niumylprop­yl)aza­nium hexa­chlorido­bis­muthate(III) monohydrate
title_full Bis(3-aza­niumylprop­yl)aza­nium hexa­chlorido­bis­muthate(III) monohydrate
title_fullStr Bis(3-aza­niumylprop­yl)aza­nium hexa­chlorido­bis­muthate(III) monohydrate
title_full_unstemmed Bis(3-aza­niumylprop­yl)aza­nium hexa­chlorido­bis­muthate(III) monohydrate
title_short Bis(3-aza­niumylprop­yl)aza­nium hexa­chlorido­bis­muthate(III) monohydrate
title_sort bis(3-aza­niumylprop­yl)aza­nium hexa­chlorido­bis­muthate(iii) monohydrate
topic Metal-Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3884999/
https://www.ncbi.nlm.nih.gov/pubmed/24454174
http://dx.doi.org/10.1107/S1600536813030900
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AT chouaibhassen bis3azaniumylpropylazaniumhexachloridobismuthateiiimonohydrate
AT kamounslaheddine bis3azaniumylpropylazaniumhexachloridobismuthateiiimonohydrate

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