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Imidazolium trans-diaquadioxalatochromate(III) dihydrate
In the title hydrated molecular salt, (C(3)H(5)N(2))[Cr(C(2)O(4))(2)(H(2)O)(2)]·2H(2)O, the complete cation is generated by a crystallographic twofold rotation axis, with one C atom lying on the rotation axis. The complete anion is generated by crystallographic inversion symmetry (Cr(III) site symm...
Autores principales: | , , , |
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Formato: | Online Artículo Texto |
Lenguaje: | English |
Publicado: |
International Union of Crystallography
2013
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3885000/ https://www.ncbi.nlm.nih.gov/pubmed/24454175 http://dx.doi.org/10.1107/S160053681303078X |
Sumario: | In the title hydrated molecular salt, (C(3)H(5)N(2))[Cr(C(2)O(4))(2)(H(2)O)(2)]·2H(2)O, the complete cation is generated by a crystallographic twofold rotation axis, with one C atom lying on the rotation axis. The complete anion is generated by crystallographic inversion symmetry (Cr(III) site symmetry -1), to generate a slightly distorted CrO(6) octahedron with trans water molecules and chelating oxalate dianions. The oxalate ion is almost planar (r.m.s. deviation = 0.017 Å) and the five-membered chelate ring is a shallow envelope with the metal ion displaced by 0.126 (1) Å from the ligand atoms. The crystal structure features O—H⋯O, N—H⋯O and C—H⋯O hydrogen bonds, which link the components into a three-dimensional network. |
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