Poly[bis­(μ(2)-1,3-phenyl­enedi­amine-κ(2) N:N′)di-μ-thio­cyanato-κ(2) N:S;κ(2) S:N-cadmium]

The structure of the title polymeric compound, [Cd(SCN)(2)(C(6)H(8)N(2))(2)](n), exhibits a two-dimensional staircase-like structure parallel to (010) in which the Cd(II) atom lies on a twofold rotation axis and has a distorted octa­hedral CdS(2)N(4) geometry involving four μ-1,3-(SCN) group donors...

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Detalles Bibliográficos
Autores principales: Chemli, Rakia, Kamoun, Slaheddine, Roisnel, Thierry
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2013
Materias:
Metal-Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3885002/
https://www.ncbi.nlm.nih.gov/pubmed/24454177
http://dx.doi.org/10.1107/S1600536813031255
Descripción
Sumario:The structure of the title polymeric compound, [Cd(SCN)(2)(C(6)H(8)N(2))(2)](n), exhibits a two-dimensional staircase-like structure parallel to (010) in which the Cd(II) atom lies on a twofold rotation axis and has a distorted octa­hedral CdS(2)N(4) geometry involving four μ-1,3-(SCN) group donors and two N-atom donors from 1,3-phenyl­enedi­amine ligands, which also have twofold symmetry. The major contributions to the cohesion and the stability of this two-dimensional polymeric structure are the covalent Cd—S,N bonds and one weak intra­layer N—H⋯S hydrogen bond.

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