Poly[bis­(μ(2)-1,3-phenyl­enedi­amine-κ(2) N:N′)di-μ-thio­cyanato-κ(2) N:S;κ(2) S:N-cadmium]

The structure of the title polymeric compound, [Cd(SCN)(2)(C(6)H(8)N(2))(2)](n), exhibits a two-dimensional staircase-like structure parallel to (010) in which the Cd(II) atom lies on a twofold rotation axis and has a distorted octa­hedral CdS(2)N(4) geometry involving four μ-1,3-(SCN) group donors...

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Detalles Bibliográficos
Autores principales: Chemli, Rakia, Kamoun, Slaheddine, Roisnel, Thierry
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2013
Materias:
Metal-Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3885002/
https://www.ncbi.nlm.nih.gov/pubmed/24454177
http://dx.doi.org/10.1107/S1600536813031255
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author Chemli, Rakia
Kamoun, Slaheddine
Roisnel, Thierry
author_facet Chemli, Rakia
Kamoun, Slaheddine
Roisnel, Thierry
author_sort Chemli, Rakia
collection PubMed
description The structure of the title polymeric compound, [Cd(SCN)(2)(C(6)H(8)N(2))(2)](n), exhibits a two-dimensional staircase-like structure parallel to (010) in which the Cd(II) atom lies on a twofold rotation axis and has a distorted octa­hedral CdS(2)N(4) geometry involving four μ-1,3-(SCN) group donors and two N-atom donors from 1,3-phenyl­enedi­amine ligands, which also have twofold symmetry. The major contributions to the cohesion and the stability of this two-dimensional polymeric structure are the covalent Cd—S,N bonds and one weak intra­layer N—H⋯S hydrogen bond.
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spelling pubmed-38850022014-01-17 Poly[bis­(μ(2)-1,3-phenyl­enedi­amine-κ(2) N:N′)di-μ-thio­cyanato-κ(2) N:S;κ(2) S:N-cadmium] Chemli, Rakia Kamoun, Slaheddine Roisnel, Thierry Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers The structure of the title polymeric compound, [Cd(SCN)(2)(C(6)H(8)N(2))(2)](n), exhibits a two-dimensional staircase-like structure parallel to (010) in which the Cd(II) atom lies on a twofold rotation axis and has a distorted octa­hedral CdS(2)N(4) geometry involving four μ-1,3-(SCN) group donors and two N-atom donors from 1,3-phenyl­enedi­amine ligands, which also have twofold symmetry. The major contributions to the cohesion and the stability of this two-dimensional polymeric structure are the covalent Cd—S,N bonds and one weak intra­layer N—H⋯S hydrogen bond. International Union of Crystallography 2013-11-20 /pmc/articles/PMC3885002/ /pubmed/24454177 http://dx.doi.org/10.1107/S1600536813031255 Text en © Chemli et al. 2013 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Metal-Organic Papers
Chemli, Rakia
Kamoun, Slaheddine
Roisnel, Thierry
Poly[bis­(μ(2)-1,3-phenyl­enedi­amine-κ(2) N:N′)di-μ-thio­cyanato-κ(2) N:S;κ(2) S:N-cadmium]
title Poly[bis­(μ(2)-1,3-phenyl­enedi­amine-κ(2) N:N′)di-μ-thio­cyanato-κ(2) N:S;κ(2) S:N-cadmium]
title_full Poly[bis­(μ(2)-1,3-phenyl­enedi­amine-κ(2) N:N′)di-μ-thio­cyanato-κ(2) N:S;κ(2) S:N-cadmium]
title_fullStr Poly[bis­(μ(2)-1,3-phenyl­enedi­amine-κ(2) N:N′)di-μ-thio­cyanato-κ(2) N:S;κ(2) S:N-cadmium]
title_full_unstemmed Poly[bis­(μ(2)-1,3-phenyl­enedi­amine-κ(2) N:N′)di-μ-thio­cyanato-κ(2) N:S;κ(2) S:N-cadmium]
title_short Poly[bis­(μ(2)-1,3-phenyl­enedi­amine-κ(2) N:N′)di-μ-thio­cyanato-κ(2) N:S;κ(2) S:N-cadmium]
title_sort poly[bis­(μ(2)-1,3-phenyl­enedi­amine-κ(2) n:n′)di-μ-thio­cyanato-κ(2) n:s;κ(2) s:n-cadmium]
topic Metal-Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3885002/
https://www.ncbi.nlm.nih.gov/pubmed/24454177
http://dx.doi.org/10.1107/S1600536813031255
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AT roisnelthierry polybism213phenylenediaminek2nndimthiocyanatok2nsk2sncadmium

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