[6,6′-Bis(1,1-di­methyl­eth­yl)-4,4′-dimethyl-2,2′-methyl­enediphenolato-κ(2) O,O′]di­chlorido­(9H-fluoren-9-ol-κO)titanium(IV)–fluorene–diethyl ether (1/0.5/1)

The title adduct, [TiCl(2)(C(23)H(30)O(2))(C(13)H(10)O]·0.5C(13)H(10)·C(4)H(10)O, is a monomer with a trigonal–bypyramidal coordination sphere of the Ti(IV) atom in which the ligand O atoms of the bidentate diphenolate anion are located in both apical and equatorial positions. Chloride ligands occup...

Descripción completa

Detalles Bibliográficos
Autores principales: Nielson, Alastair J., Shen, Chaohong, Waters, Joyce M.
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2013
Materias:
Metal-Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3885004/
https://www.ncbi.nlm.nih.gov/pubmed/24454179
http://dx.doi.org/10.1107/S1600536813030249
_version_ 1782298688822968320
author Nielson, Alastair J.
Shen, Chaohong
Waters, Joyce M.
author_facet Nielson, Alastair J.
Shen, Chaohong
Waters, Joyce M.
author_sort Nielson, Alastair J.
collection PubMed
description The title adduct, [TiCl(2)(C(23)H(30)O(2))(C(13)H(10)O]·0.5C(13)H(10)·C(4)H(10)O, is a monomer with a trigonal–bypyramidal coordination sphere of the Ti(IV) atom in which the ligand O atoms of the bidentate diphenolate anion are located in both apical and equatorial positions. Chloride ligands occupy the remaining two equatorial sites of the trigonal bypyramid with the fluoren-9-ol O atom occupying the other apical site. The hy­droxy group H atom of this latter group is hydrogen bonded to an O atom of a non-coordinating diethyl ether mol­ecule. The title compound also contains a further fluorene solvent mol­ecule, which lies across a centre of symmetry and which is equally disordered over an inversion centre.
format Online
Article
Text
id pubmed-3885004
institution National Center for Biotechnology Information
language English
publishDate 2013
publisher International Union of Crystallography
record_format MEDLINE/PubMed
spelling pubmed-38850042014-01-17 [6,6′-Bis(1,1-di­methyl­eth­yl)-4,4′-dimethyl-2,2′-methyl­enediphenolato-κ(2) O,O′]di­chlorido­(9H-fluoren-9-ol-κO)titanium(IV)–fluorene–diethyl ether (1/0.5/1) Nielson, Alastair J. Shen, Chaohong Waters, Joyce M. Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers The title adduct, [TiCl(2)(C(23)H(30)O(2))(C(13)H(10)O]·0.5C(13)H(10)·C(4)H(10)O, is a monomer with a trigonal–bypyramidal coordination sphere of the Ti(IV) atom in which the ligand O atoms of the bidentate diphenolate anion are located in both apical and equatorial positions. Chloride ligands occupy the remaining two equatorial sites of the trigonal bypyramid with the fluoren-9-ol O atom occupying the other apical site. The hy­droxy group H atom of this latter group is hydrogen bonded to an O atom of a non-coordinating diethyl ether mol­ecule. The title compound also contains a further fluorene solvent mol­ecule, which lies across a centre of symmetry and which is equally disordered over an inversion centre. International Union of Crystallography 2013-11-20 /pmc/articles/PMC3885004/ /pubmed/24454179 http://dx.doi.org/10.1107/S1600536813030249 Text en © Nielson et al. 2013 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Metal-Organic Papers
Nielson, Alastair J.
Shen, Chaohong
Waters, Joyce M.
[6,6′-Bis(1,1-di­methyl­eth­yl)-4,4′-dimethyl-2,2′-methyl­enediphenolato-κ(2) O,O′]di­chlorido­(9H-fluoren-9-ol-κO)titanium(IV)–fluorene–diethyl ether (1/0.5/1)
title [6,6′-Bis(1,1-di­methyl­eth­yl)-4,4′-dimethyl-2,2′-methyl­enediphenolato-κ(2) O,O′]di­chlorido­(9H-fluoren-9-ol-κO)titanium(IV)–fluorene–diethyl ether (1/0.5/1)
title_full [6,6′-Bis(1,1-di­methyl­eth­yl)-4,4′-dimethyl-2,2′-methyl­enediphenolato-κ(2) O,O′]di­chlorido­(9H-fluoren-9-ol-κO)titanium(IV)–fluorene–diethyl ether (1/0.5/1)
title_fullStr [6,6′-Bis(1,1-di­methyl­eth­yl)-4,4′-dimethyl-2,2′-methyl­enediphenolato-κ(2) O,O′]di­chlorido­(9H-fluoren-9-ol-κO)titanium(IV)–fluorene–diethyl ether (1/0.5/1)
title_full_unstemmed [6,6′-Bis(1,1-di­methyl­eth­yl)-4,4′-dimethyl-2,2′-methyl­enediphenolato-κ(2) O,O′]di­chlorido­(9H-fluoren-9-ol-κO)titanium(IV)–fluorene–diethyl ether (1/0.5/1)
title_short [6,6′-Bis(1,1-di­methyl­eth­yl)-4,4′-dimethyl-2,2′-methyl­enediphenolato-κ(2) O,O′]di­chlorido­(9H-fluoren-9-ol-κO)titanium(IV)–fluorene–diethyl ether (1/0.5/1)
title_sort [6,6′-bis(1,1-di­methyl­eth­yl)-4,4′-dimethyl-2,2′-methyl­enediphenolato-κ(2) o,o′]di­chlorido­(9h-fluoren-9-ol-κo)titanium(iv)–fluorene–diethyl ether (1/0.5/1)
topic Metal-Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3885004/
https://www.ncbi.nlm.nih.gov/pubmed/24454179
http://dx.doi.org/10.1107/S1600536813030249
work_keys_str_mv AT nielsonalastairj 66bis11dimethylethyl44dimethyl22methylenediphenolatok2oodichlorido9hfluoren9olkotitaniumivfluorenediethylether1051
AT shenchaohong 66bis11dimethylethyl44dimethyl22methylenediphenolatok2oodichlorido9hfluoren9olkotitaniumivfluorenediethylether1051
AT watersjoycem 66bis11dimethylethyl44dimethyl22methylenediphenolatok2oodichlorido9hfluoren9olkotitaniumivfluorenediethylether1051

Ejemplares similares