Bis(2-meth­oxy­anilinium) hexa­bromido­stannate(IV) dihydrate

The asymmetric unit of the title compound, (C(7)H(10)NO)(2)[SnBr(6)]·2H(2)O, contains one cation, one half-dianion and one lattice water mol­ecule. The [SnBr(6)](2−) dianion, located on an inversion center, exhibits a highly distorted octa­hedral coordination environment, with Sn—Br bond lengths ran...

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Detalles Bibliográficos
Autores principales: Chouaib, Hassen, Karoui, Sahel, Kamoun, Slaheddine, Michaud, Francois
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2013
Materias:
Metal-Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3885007/
https://www.ncbi.nlm.nih.gov/pubmed/24454182
http://dx.doi.org/10.1107/S1600536813031681
Descripción
Sumario:The asymmetric unit of the title compound, (C(7)H(10)NO)(2)[SnBr(6)]·2H(2)O, contains one cation, one half-dianion and one lattice water mol­ecule. The [SnBr(6)](2−) dianion, located on an inversion center, exhibits a highly distorted octa­hedral coordination environment, with Sn—Br bond lengths ranging from 2.2426 (9) to 3.0886 (13) Å. In the crystal, O—H⋯Br, N—H⋯Br, N—H⋯O and C—H⋯Br hydrogen bonds consolidate the packing, which can be described as consisting of alternating anionic (containing dianions and lattice water mol­ecules) and cationic layers parallel to ab plane.

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