Bis(2-meth­oxy­anilinium) hexa­bromido­stannate(IV) dihydrate

The asymmetric unit of the title compound, (C(7)H(10)NO)(2)[SnBr(6)]·2H(2)O, contains one cation, one half-dianion and one lattice water mol­ecule. The [SnBr(6)](2−) dianion, located on an inversion center, exhibits a highly distorted octa­hedral coordination environment, with Sn—Br bond lengths ran...

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Detalles Bibliográficos
Autores principales: Chouaib, Hassen, Karoui, Sahel, Kamoun, Slaheddine, Michaud, Francois
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2013
Materias:
Metal-Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3885007/
https://www.ncbi.nlm.nih.gov/pubmed/24454182
http://dx.doi.org/10.1107/S1600536813031681
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author Chouaib, Hassen
Karoui, Sahel
Kamoun, Slaheddine
Michaud, Francois
author_facet Chouaib, Hassen
Karoui, Sahel
Kamoun, Slaheddine
Michaud, Francois
author_sort Chouaib, Hassen
collection PubMed
description The asymmetric unit of the title compound, (C(7)H(10)NO)(2)[SnBr(6)]·2H(2)O, contains one cation, one half-dianion and one lattice water mol­ecule. The [SnBr(6)](2−) dianion, located on an inversion center, exhibits a highly distorted octa­hedral coordination environment, with Sn—Br bond lengths ranging from 2.2426 (9) to 3.0886 (13) Å. In the crystal, O—H⋯Br, N—H⋯Br, N—H⋯O and C—H⋯Br hydrogen bonds consolidate the packing, which can be described as consisting of alternating anionic (containing dianions and lattice water mol­ecules) and cationic layers parallel to ab plane.
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spelling pubmed-38850072014-01-17 Bis(2-meth­oxy­anilinium) hexa­bromido­stannate(IV) dihydrate Chouaib, Hassen Karoui, Sahel Kamoun, Slaheddine Michaud, Francois Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers The asymmetric unit of the title compound, (C(7)H(10)NO)(2)[SnBr(6)]·2H(2)O, contains one cation, one half-dianion and one lattice water mol­ecule. The [SnBr(6)](2−) dianion, located on an inversion center, exhibits a highly distorted octa­hedral coordination environment, with Sn—Br bond lengths ranging from 2.2426 (9) to 3.0886 (13) Å. In the crystal, O—H⋯Br, N—H⋯Br, N—H⋯O and C—H⋯Br hydrogen bonds consolidate the packing, which can be described as consisting of alternating anionic (containing dianions and lattice water mol­ecules) and cationic layers parallel to ab plane. International Union of Crystallography 2013-11-23 /pmc/articles/PMC3885007/ /pubmed/24454182 http://dx.doi.org/10.1107/S1600536813031681 Text en © Chouaib et al. 2013 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Metal-Organic Papers
Chouaib, Hassen
Karoui, Sahel
Kamoun, Slaheddine
Michaud, Francois
Bis(2-meth­oxy­anilinium) hexa­bromido­stannate(IV) dihydrate
title Bis(2-meth­oxy­anilinium) hexa­bromido­stannate(IV) dihydrate
title_full Bis(2-meth­oxy­anilinium) hexa­bromido­stannate(IV) dihydrate
title_fullStr Bis(2-meth­oxy­anilinium) hexa­bromido­stannate(IV) dihydrate
title_full_unstemmed Bis(2-meth­oxy­anilinium) hexa­bromido­stannate(IV) dihydrate
title_short Bis(2-meth­oxy­anilinium) hexa­bromido­stannate(IV) dihydrate
title_sort bis(2-meth­oxy­anilinium) hexa­bromido­stannate(iv) dihydrate
topic Metal-Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3885007/
https://www.ncbi.nlm.nih.gov/pubmed/24454182
http://dx.doi.org/10.1107/S1600536813031681
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AT michaudfrancois bis2methoxyaniliniumhexabromidostannateivdihydrate

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