Bis{μ(4)-N-[phen­yl(pyridin-2-yl­aza­nid­yl)meth­yl]pyridin-2-aminido}tetra­kis(tetra­hydro­furan)­tetra­lithium

The title complex, [Li(4)(C(17)H(14)N(4))(2)(C(4)H(8)O)(4)], bears a novel tetra­dentate di­amido ligand. In the tetra­nuclear centrosymmetric complex mol­ecule, the metal atoms exhibit two kinds of coordination modes. The middle two Li(+) cations are coord­inated by four N (ligand) and one O (tetra...

Descripción completa

Detalles Bibliográficos
Autor principal: Chen, Juan
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2013
Materias:
Metal-Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3885009/
https://www.ncbi.nlm.nih.gov/pubmed/24454184
http://dx.doi.org/10.1107/S1600536813031838
_version_ 1782298690319286272
author Chen, Juan
author_facet Chen, Juan
author_sort Chen, Juan
collection PubMed
description The title complex, [Li(4)(C(17)H(14)N(4))(2)(C(4)H(8)O)(4)], bears a novel tetra­dentate di­amido ligand. In the tetra­nuclear centrosymmetric complex mol­ecule, the metal atoms exhibit two kinds of coordination modes. The middle two Li(+) cations are coord­inated by four N (ligand) and one O (tetra­hydro­furan, THF) atoms, resulting in a distorted square-pyramidal geometry. The outer two Li(+) cations are in distorted tetra­hedral environments consisting of three N (ligand) and one O (THF) atoms. The Li—N bond lengths vary from 2.020 (7) to 2.441 (6)Å.
format Online
Article
Text
id pubmed-3885009
institution National Center for Biotechnology Information
language English
publishDate 2013
publisher International Union of Crystallography
record_format MEDLINE/PubMed
spelling pubmed-38850092014-01-17 Bis{μ(4)-N-[phen­yl(pyridin-2-yl­aza­nid­yl)meth­yl]pyridin-2-aminido}tetra­kis(tetra­hydro­furan)­tetra­lithium Chen, Juan Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers The title complex, [Li(4)(C(17)H(14)N(4))(2)(C(4)H(8)O)(4)], bears a novel tetra­dentate di­amido ligand. In the tetra­nuclear centrosymmetric complex mol­ecule, the metal atoms exhibit two kinds of coordination modes. The middle two Li(+) cations are coord­inated by four N (ligand) and one O (tetra­hydro­furan, THF) atoms, resulting in a distorted square-pyramidal geometry. The outer two Li(+) cations are in distorted tetra­hedral environments consisting of three N (ligand) and one O (THF) atoms. The Li—N bond lengths vary from 2.020 (7) to 2.441 (6)Å. International Union of Crystallography 2013-11-27 /pmc/articles/PMC3885009/ /pubmed/24454184 http://dx.doi.org/10.1107/S1600536813031838 Text en © Juan Chen 2013 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Metal-Organic Papers
Chen, Juan
Bis{μ(4)-N-[phen­yl(pyridin-2-yl­aza­nid­yl)meth­yl]pyridin-2-aminido}tetra­kis(tetra­hydro­furan)­tetra­lithium
title Bis{μ(4)-N-[phen­yl(pyridin-2-yl­aza­nid­yl)meth­yl]pyridin-2-aminido}tetra­kis(tetra­hydro­furan)­tetra­lithium
title_full Bis{μ(4)-N-[phen­yl(pyridin-2-yl­aza­nid­yl)meth­yl]pyridin-2-aminido}tetra­kis(tetra­hydro­furan)­tetra­lithium
title_fullStr Bis{μ(4)-N-[phen­yl(pyridin-2-yl­aza­nid­yl)meth­yl]pyridin-2-aminido}tetra­kis(tetra­hydro­furan)­tetra­lithium
title_full_unstemmed Bis{μ(4)-N-[phen­yl(pyridin-2-yl­aza­nid­yl)meth­yl]pyridin-2-aminido}tetra­kis(tetra­hydro­furan)­tetra­lithium
title_short Bis{μ(4)-N-[phen­yl(pyridin-2-yl­aza­nid­yl)meth­yl]pyridin-2-aminido}tetra­kis(tetra­hydro­furan)­tetra­lithium
title_sort bis{μ(4)-n-[phen­yl(pyridin-2-yl­aza­nid­yl)meth­yl]pyridin-2-aminido}tetra­kis(tetra­hydro­furan)­tetra­lithium
topic Metal-Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3885009/
https://www.ncbi.nlm.nih.gov/pubmed/24454184
http://dx.doi.org/10.1107/S1600536813031838
work_keys_str_mv AT chenjuan bism4nphenylpyridin2ylazanidylmethylpyridin2aminidotetrakistetrahydrofurantetralithium

Ejemplares similares