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Bis(2,9-dimethyl-1,10-phenanthroline)copper(I) pentacyanidonitrosoferrate(II)
The asymmetric unit of the title complex [Cu(C(14)H(12)N(2))(2)](2)[Fe(CN)(5)(NO)], consists of a [Cu(dmp)(2)](+) cation (dmp is 2,9-dimethyl-1,10-phenanthroline) and half an [Fe(CN)(5)(NO)](2−) anion. The anion is disordered across an inversion center with the Fe(II) ion slightly offset (ca 0.205Å)...
Autores principales: | , , , |
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Formato: | Online Artículo Texto |
Lenguaje: | English |
Publicado: |
International Union of Crystallography
2013
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3885010/ https://www.ncbi.nlm.nih.gov/pubmed/24454185 http://dx.doi.org/10.1107/S1600536813031760 |
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author | Rusanova, Julia A. Kozachuk, Olesia V. Semenaka, Valentyna V. Dyakonenko, Viktoriya V. |
author_facet | Rusanova, Julia A. Kozachuk, Olesia V. Semenaka, Valentyna V. Dyakonenko, Viktoriya V. |
author_sort | Rusanova, Julia A. |
collection | PubMed |
description | The asymmetric unit of the title complex [Cu(C(14)H(12)N(2))(2)](2)[Fe(CN)(5)(NO)], consists of a [Cu(dmp)(2)](+) cation (dmp is 2,9-dimethyl-1,10-phenanthroline) and half an [Fe(CN)(5)(NO)](2−) anion. The anion is disordered across an inversion center with the Fe(II) ion slightly offset (ca 0.205Å) from the inversion center in the direction of the disordered trans-coordinating CN/NO ligands. The anion has a distorted octahedral coordination geometry. The Cu(I) ion is coordinated by two phenanthroline ligands in a distorted tetrahedral geometry. The dihedral angle between the phenanthroline ligands is 77.16 (4) Å. In the crystal, the cations are connected to the anions by weak C—H⋯N hydrogen bonds. In addition, weak π–π stacking interactions are observed, with centroid–centroid distances in the range 3.512 (3)–3.859 (3) Å. |
format | Online Article Text |
id | pubmed-3885010 |
institution | National Center for Biotechnology Information |
language | English |
publishDate | 2013 |
publisher | International Union of Crystallography |
record_format | MEDLINE/PubMed |
spelling | pubmed-38850102014-01-17 Bis(2,9-dimethyl-1,10-phenanthroline)copper(I) pentacyanidonitrosoferrate(II) Rusanova, Julia A. Kozachuk, Olesia V. Semenaka, Valentyna V. Dyakonenko, Viktoriya V. Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers The asymmetric unit of the title complex [Cu(C(14)H(12)N(2))(2)](2)[Fe(CN)(5)(NO)], consists of a [Cu(dmp)(2)](+) cation (dmp is 2,9-dimethyl-1,10-phenanthroline) and half an [Fe(CN)(5)(NO)](2−) anion. The anion is disordered across an inversion center with the Fe(II) ion slightly offset (ca 0.205Å) from the inversion center in the direction of the disordered trans-coordinating CN/NO ligands. The anion has a distorted octahedral coordination geometry. The Cu(I) ion is coordinated by two phenanthroline ligands in a distorted tetrahedral geometry. The dihedral angle between the phenanthroline ligands is 77.16 (4) Å. In the crystal, the cations are connected to the anions by weak C—H⋯N hydrogen bonds. In addition, weak π–π stacking interactions are observed, with centroid–centroid distances in the range 3.512 (3)–3.859 (3) Å. International Union of Crystallography 2013-11-27 /pmc/articles/PMC3885010/ /pubmed/24454185 http://dx.doi.org/10.1107/S1600536813031760 Text en © Rusanova et al. 2013 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited. |
spellingShingle | Metal-Organic Papers Rusanova, Julia A. Kozachuk, Olesia V. Semenaka, Valentyna V. Dyakonenko, Viktoriya V. Bis(2,9-dimethyl-1,10-phenanthroline)copper(I) pentacyanidonitrosoferrate(II) |
title | Bis(2,9-dimethyl-1,10-phenanthroline)copper(I) pentacyanidonitrosoferrate(II) |
title_full | Bis(2,9-dimethyl-1,10-phenanthroline)copper(I) pentacyanidonitrosoferrate(II) |
title_fullStr | Bis(2,9-dimethyl-1,10-phenanthroline)copper(I) pentacyanidonitrosoferrate(II) |
title_full_unstemmed | Bis(2,9-dimethyl-1,10-phenanthroline)copper(I) pentacyanidonitrosoferrate(II) |
title_short | Bis(2,9-dimethyl-1,10-phenanthroline)copper(I) pentacyanidonitrosoferrate(II) |
title_sort | bis(2,9-dimethyl-1,10-phenanthroline)copper(i) pentacyanidonitrosoferrate(ii) |
topic | Metal-Organic Papers |
url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3885010/ https://www.ncbi.nlm.nih.gov/pubmed/24454185 http://dx.doi.org/10.1107/S1600536813031760 |
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