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Bis(2,9-dimethyl-1,10-phenanthroline)copper(I) penta­cyanido­nitro­soferrate(II)

The asymmetric unit of the title complex [Cu(C(14)H(12)N(2))(2)](2)[Fe(CN)(5)(NO)], consists of a [Cu(dmp)(2)](+) cation (dmp is 2,9-dimethyl-1,10-phenanthroline) and half an [Fe(CN)(5)(NO)](2−) anion. The anion is disordered across an inversion center with the Fe(II) ion slightly offset (ca 0.205Å)...

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Autores principales: Rusanova, Julia A., Kozachuk, Olesia V., Semenaka, Valentyna V., Dyakonenko, Viktoriya V.
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2013
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3885010/
https://www.ncbi.nlm.nih.gov/pubmed/24454185
http://dx.doi.org/10.1107/S1600536813031760
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author Rusanova, Julia A.
Kozachuk, Olesia V.
Semenaka, Valentyna V.
Dyakonenko, Viktoriya V.
author_facet Rusanova, Julia A.
Kozachuk, Olesia V.
Semenaka, Valentyna V.
Dyakonenko, Viktoriya V.
author_sort Rusanova, Julia A.
collection PubMed
description The asymmetric unit of the title complex [Cu(C(14)H(12)N(2))(2)](2)[Fe(CN)(5)(NO)], consists of a [Cu(dmp)(2)](+) cation (dmp is 2,9-dimethyl-1,10-phenanthroline) and half an [Fe(CN)(5)(NO)](2−) anion. The anion is disordered across an inversion center with the Fe(II) ion slightly offset (ca 0.205Å) from the inversion center in the direction of the disordered trans-coordinating CN/NO ligands. The anion has a distorted octa­hedral coordination geometry. The Cu(I) ion is coordinated by two phenanthroline ligands in a distorted tetra­hedral geometry. The dihedral angle between the phenanthroline ligands is 77.16 (4) Å. In the crystal, the cations are connected to the anions by weak C—H⋯N hydrogen bonds. In addition, weak π–π stacking inter­actions are observed, with centroid–centroid distances in the range 3.512 (3)–3.859 (3) Å.
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spelling pubmed-38850102014-01-17 Bis(2,9-dimethyl-1,10-phenanthroline)copper(I) penta­cyanido­nitro­soferrate(II) Rusanova, Julia A. Kozachuk, Olesia V. Semenaka, Valentyna V. Dyakonenko, Viktoriya V. Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers The asymmetric unit of the title complex [Cu(C(14)H(12)N(2))(2)](2)[Fe(CN)(5)(NO)], consists of a [Cu(dmp)(2)](+) cation (dmp is 2,9-dimethyl-1,10-phenanthroline) and half an [Fe(CN)(5)(NO)](2−) anion. The anion is disordered across an inversion center with the Fe(II) ion slightly offset (ca 0.205Å) from the inversion center in the direction of the disordered trans-coordinating CN/NO ligands. The anion has a distorted octa­hedral coordination geometry. The Cu(I) ion is coordinated by two phenanthroline ligands in a distorted tetra­hedral geometry. The dihedral angle between the phenanthroline ligands is 77.16 (4) Å. In the crystal, the cations are connected to the anions by weak C—H⋯N hydrogen bonds. In addition, weak π–π stacking inter­actions are observed, with centroid–centroid distances in the range 3.512 (3)–3.859 (3) Å. International Union of Crystallography 2013-11-27 /pmc/articles/PMC3885010/ /pubmed/24454185 http://dx.doi.org/10.1107/S1600536813031760 Text en © Rusanova et al. 2013 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Metal-Organic Papers
Rusanova, Julia A.
Kozachuk, Olesia V.
Semenaka, Valentyna V.
Dyakonenko, Viktoriya V.
Bis(2,9-dimethyl-1,10-phenanthroline)copper(I) penta­cyanido­nitro­soferrate(II)
title Bis(2,9-dimethyl-1,10-phenanthroline)copper(I) penta­cyanido­nitro­soferrate(II)
title_full Bis(2,9-dimethyl-1,10-phenanthroline)copper(I) penta­cyanido­nitro­soferrate(II)
title_fullStr Bis(2,9-dimethyl-1,10-phenanthroline)copper(I) penta­cyanido­nitro­soferrate(II)
title_full_unstemmed Bis(2,9-dimethyl-1,10-phenanthroline)copper(I) penta­cyanido­nitro­soferrate(II)
title_short Bis(2,9-dimethyl-1,10-phenanthroline)copper(I) penta­cyanido­nitro­soferrate(II)
title_sort bis(2,9-dimethyl-1,10-phenanthroline)copper(i) penta­cyanido­nitro­soferrate(ii)
topic Metal-Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3885010/
https://www.ncbi.nlm.nih.gov/pubmed/24454185
http://dx.doi.org/10.1107/S1600536813031760
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