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{4-Chloro-N′-[(2-oxidonaphthalen-1-yl-κO)methylidene]benzohydrazidato-κ(2) N′,O}dimethyltin(IV)
In the title complex, [Sn(CH(3))(2)(C(18)H(11)ClN(2)O(2))], the Sn(IV) ion is coordinated by two O atoms and an N atom from a 4-chloro-N′-[(2-oxidonaphthalen-1-yl)methylidene]benzohydrazidate ligand and two C atoms from two methyl ligands in a distorted trigonal–bipyramidal geometry [Sn—O = 2.092 (...
Autores principales: | , , |
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Formato: | Online Artículo Texto |
Lenguaje: | English |
Publicado: |
International Union of Crystallography
2013
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3885012/ https://www.ncbi.nlm.nih.gov/pubmed/24454187 http://dx.doi.org/10.1107/S1600536813031826 |
Sumario: | In the title complex, [Sn(CH(3))(2)(C(18)H(11)ClN(2)O(2))], the Sn(IV) ion is coordinated by two O atoms and an N atom from a 4-chloro-N′-[(2-oxidonaphthalen-1-yl)methylidene]benzohydrazidate ligand and two C atoms from two methyl ligands in a distorted trigonal–bipyramidal geometry [Sn—O = 2.092 (3) and 2.144 (3) Å; Sn—N = 2.160 (4) Å]. The dihedral angle between the naphthalene ring system and the benzene ring is 8.6 (2)°. In the crystal, adjacent molecules are linked by weak C—H⋯O hydrogen bonds, forming a chain along the b-axis direction. |
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