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{4-Chloro-N′-[(2-oxidonaphthalen-1-yl-κO)methyl­idene]benzohydrazidato-κ(2) N′,O}di­methyl­tin(IV)

In the title complex, [Sn(CH(3))(2)(C(18)H(11)ClN(2)O(2))], the Sn(IV) ion is coordinated by two O atoms and an N atom from a 4-chloro-N′-[(2-oxidonaphthalen-1-yl)methyl­idene]benzohydrazidate ligand and two C atoms from two methyl ligands in a distorted trigonal–bipyramidal geometry [Sn—O = 2.092 (...

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Detalles Bibliográficos
Autores principales: Cui, Jichun, Qiao, Yanling, Wang, Fei
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2013
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3885012/
https://www.ncbi.nlm.nih.gov/pubmed/24454187
http://dx.doi.org/10.1107/S1600536813031826
Descripción
Sumario:In the title complex, [Sn(CH(3))(2)(C(18)H(11)ClN(2)O(2))], the Sn(IV) ion is coordinated by two O atoms and an N atom from a 4-chloro-N′-[(2-oxidonaphthalen-1-yl)methyl­idene]benzohydrazidate ligand and two C atoms from two methyl ligands in a distorted trigonal–bipyramidal geometry [Sn—O = 2.092 (3) and 2.144 (3) Å; Sn—N = 2.160 (4) Å]. The dihedral angle between the naphthalene ring system and the benzene ring is 8.6 (2)°. In the crystal, adjacent mol­ecules are linked by weak C—H⋯O hydrogen bonds, forming a chain along the b-axis direction.