{4-Chloro-N′-[(2-oxidonaphthalen-1-yl-κO)methyl­idene]benzohydrazidato-κ(2) N′,O}di­methyl­tin(IV)

In the title complex, [Sn(CH(3))(2)(C(18)H(11)ClN(2)O(2))], the Sn(IV) ion is coordinated by two O atoms and an N atom from a 4-chloro-N′-[(2-oxidonaphthalen-1-yl)methyl­idene]benzohydrazidate ligand and two C atoms from two methyl ligands in a distorted trigonal–bipyramidal geometry [Sn—O = 2.092 (...

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Detalles Bibliográficos
Autores principales: Cui, Jichun, Qiao, Yanling, Wang, Fei
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2013
Materias:
Metal-Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3885012/
https://www.ncbi.nlm.nih.gov/pubmed/24454187
http://dx.doi.org/10.1107/S1600536813031826
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author Cui, Jichun
Qiao, Yanling
Wang, Fei
author_facet Cui, Jichun
Qiao, Yanling
Wang, Fei
author_sort Cui, Jichun
collection PubMed
description In the title complex, [Sn(CH(3))(2)(C(18)H(11)ClN(2)O(2))], the Sn(IV) ion is coordinated by two O atoms and an N atom from a 4-chloro-N′-[(2-oxidonaphthalen-1-yl)methyl­idene]benzohydrazidate ligand and two C atoms from two methyl ligands in a distorted trigonal–bipyramidal geometry [Sn—O = 2.092 (3) and 2.144 (3) Å; Sn—N = 2.160 (4) Å]. The dihedral angle between the naphthalene ring system and the benzene ring is 8.6 (2)°. In the crystal, adjacent mol­ecules are linked by weak C—H⋯O hydrogen bonds, forming a chain along the b-axis direction.
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spelling pubmed-38850122014-01-17 {4-Chloro-N′-[(2-oxidonaphthalen-1-yl-κO)methyl­idene]benzohydrazidato-κ(2) N′,O}di­methyl­tin(IV) Cui, Jichun Qiao, Yanling Wang, Fei Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers In the title complex, [Sn(CH(3))(2)(C(18)H(11)ClN(2)O(2))], the Sn(IV) ion is coordinated by two O atoms and an N atom from a 4-chloro-N′-[(2-oxidonaphthalen-1-yl)methyl­idene]benzohydrazidate ligand and two C atoms from two methyl ligands in a distorted trigonal–bipyramidal geometry [Sn—O = 2.092 (3) and 2.144 (3) Å; Sn—N = 2.160 (4) Å]. The dihedral angle between the naphthalene ring system and the benzene ring is 8.6 (2)°. In the crystal, adjacent mol­ecules are linked by weak C—H⋯O hydrogen bonds, forming a chain along the b-axis direction. International Union of Crystallography 2013-11-30 /pmc/articles/PMC3885012/ /pubmed/24454187 http://dx.doi.org/10.1107/S1600536813031826 Text en © Cui et al. 2013 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Metal-Organic Papers
Cui, Jichun
Qiao, Yanling
Wang, Fei
{4-Chloro-N′-[(2-oxidonaphthalen-1-yl-κO)methyl­idene]benzohydrazidato-κ(2) N′,O}di­methyl­tin(IV)
title {4-Chloro-N′-[(2-oxidonaphthalen-1-yl-κO)methyl­idene]benzohydrazidato-κ(2) N′,O}di­methyl­tin(IV)
title_full {4-Chloro-N′-[(2-oxidonaphthalen-1-yl-κO)methyl­idene]benzohydrazidato-κ(2) N′,O}di­methyl­tin(IV)
title_fullStr {4-Chloro-N′-[(2-oxidonaphthalen-1-yl-κO)methyl­idene]benzohydrazidato-κ(2) N′,O}di­methyl­tin(IV)
title_full_unstemmed {4-Chloro-N′-[(2-oxidonaphthalen-1-yl-κO)methyl­idene]benzohydrazidato-κ(2) N′,O}di­methyl­tin(IV)
title_short {4-Chloro-N′-[(2-oxidonaphthalen-1-yl-κO)methyl­idene]benzohydrazidato-κ(2) N′,O}di­methyl­tin(IV)
title_sort {4-chloro-n′-[(2-oxidonaphthalen-1-yl-κo)methyl­idene]benzohydrazidato-κ(2) n′,o}di­methyl­tin(iv)
topic Metal-Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3885012/
https://www.ncbi.nlm.nih.gov/pubmed/24454187
http://dx.doi.org/10.1107/S1600536813031826
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AT qiaoyanling 4chloron2oxidonaphthalen1ylkomethylidenebenzohydrazidatok2nodimethyltiniv
AT wangfei 4chloron2oxidonaphthalen1ylkomethylidenebenzohydrazidatok2nodimethyltiniv

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