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catena-Poly[[tetra-μ-formato-κ(8) O:O′-dicopper(II)]-μ-hexamethylenetetramine-κ(2) N (1):N (5)]
In the title polymeric compound, [Cu(2)(HCO(2))(4)(C(6)H(12)N(4))](n), the Cu(II) atom is five-coordinated in a square-pyramidal geometry that is defined by four O atoms from four formate ligands and one N atom from a hexamethylenetetramine ligand. The two Cu(II) atoms are separated by 2.6850 (7...
| Autores principales: | , , , , |
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| Formato: | Online Artículo Texto |
| Lenguaje: | English |
| Publicado: |
International Union of Crystallography
2013
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| Materias: | |
| Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3885013/ https://www.ncbi.nlm.nih.gov/pubmed/24454188 http://dx.doi.org/10.1107/S160053681303184X |
| _version_ | 1782298691283976192 |
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| author | Cao, Jianfang Huang, Ziping Cao, Changnian Cheng, Chunchun Sun, Chunyan |
| author_facet | Cao, Jianfang Huang, Ziping Cao, Changnian Cheng, Chunchun Sun, Chunyan |
| author_sort | Cao, Jianfang |
| collection | PubMed |
| description | In the title polymeric compound, [Cu(2)(HCO(2))(4)(C(6)H(12)N(4))](n), the Cu(II) atom is five-coordinated in a square-pyramidal geometry that is defined by four O atoms from four formate ligands and one N atom from a hexamethylenetetramine ligand. The two Cu(II) atoms are separated by 2.6850 (7) Å, and together with the four formate ligands they form a paddle-wheel unit. The hexamine ligand uses only two of its four N atoms to link Cu(2) cluster units, affording a zigzag chain running along the b-axis direction. The hexamine ligand lies on a mirror plane. |
| format | Online Article Text |
| id | pubmed-3885013 |
| institution | National Center for Biotechnology Information |
| language | English |
| publishDate | 2013 |
| publisher | International Union of Crystallography |
| record_format | MEDLINE/PubMed |
| spelling | pubmed-38850132014-01-17 catena-Poly[[tetra-μ-formato-κ(8) O:O′-dicopper(II)]-μ-hexamethylenetetramine-κ(2) N (1):N (5)] Cao, Jianfang Huang, Ziping Cao, Changnian Cheng, Chunchun Sun, Chunyan Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers In the title polymeric compound, [Cu(2)(HCO(2))(4)(C(6)H(12)N(4))](n), the Cu(II) atom is five-coordinated in a square-pyramidal geometry that is defined by four O atoms from four formate ligands and one N atom from a hexamethylenetetramine ligand. The two Cu(II) atoms are separated by 2.6850 (7) Å, and together with the four formate ligands they form a paddle-wheel unit. The hexamine ligand uses only two of its four N atoms to link Cu(2) cluster units, affording a zigzag chain running along the b-axis direction. The hexamine ligand lies on a mirror plane. International Union of Crystallography 2013-11-30 /pmc/articles/PMC3885013/ /pubmed/24454188 http://dx.doi.org/10.1107/S160053681303184X Text en © Cao et al. 2013 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited. |
| spellingShingle | Metal-Organic Papers Cao, Jianfang Huang, Ziping Cao, Changnian Cheng, Chunchun Sun, Chunyan catena-Poly[[tetra-μ-formato-κ(8) O:O′-dicopper(II)]-μ-hexamethylenetetramine-κ(2) N (1):N (5)] |
| title |
catena-Poly[[tetra-μ-formato-κ(8)
O:O′-dicopper(II)]-μ-hexamethylenetetramine-κ(2)
N
(1):N
(5)] |
| title_full |
catena-Poly[[tetra-μ-formato-κ(8)
O:O′-dicopper(II)]-μ-hexamethylenetetramine-κ(2)
N
(1):N
(5)] |
| title_fullStr |
catena-Poly[[tetra-μ-formato-κ(8)
O:O′-dicopper(II)]-μ-hexamethylenetetramine-κ(2)
N
(1):N
(5)] |
| title_full_unstemmed |
catena-Poly[[tetra-μ-formato-κ(8)
O:O′-dicopper(II)]-μ-hexamethylenetetramine-κ(2)
N
(1):N
(5)] |
| title_short |
catena-Poly[[tetra-μ-formato-κ(8)
O:O′-dicopper(II)]-μ-hexamethylenetetramine-κ(2)
N
(1):N
(5)] |
| title_sort | catena-poly[[tetra-μ-formato-κ(8)
o:o′-dicopper(ii)]-μ-hexamethylenetetramine-κ(2)
n
(1):n
(5)] |
| topic | Metal-Organic Papers |
| url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3885013/ https://www.ncbi.nlm.nih.gov/pubmed/24454188 http://dx.doi.org/10.1107/S160053681303184X |
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