Ethyl 2-[6-(4-methyl­benzo­yl)-7-phenyl-2,3-di­hydro-1H-pyrrolizin-5-yl]-2-oxo­acetate

In the title compound, C(25)H(23)NO(4), the pyrrolizine ring is approximately planar with an r.m.s deviation from planarity of 0.0053 Å, while the fused di­hydro­pyrrolizine ring adopts an envelope conformation with the C atom connected to two CH(2) as the flap. The dihedral angles between the fused...

Descripción completa

Detalles Bibliográficos
Autores principales: Zhong, Jia-liang, Sun, Wen-xia, Zhang, Fu-li, Liu, Li-hong, Liu, He
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2013
Materias:
Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3885017/
https://www.ncbi.nlm.nih.gov/pubmed/24454192
http://dx.doi.org/10.1107/S1600536813029401
Descripción
Sumario:In the title compound, C(25)H(23)NO(4), the pyrrolizine ring is approximately planar with an r.m.s deviation from planarity of 0.0053 Å, while the fused di­hydro­pyrrolizine ring adopts an envelope conformation with the C atom connected to two CH(2) as the flap. The dihedral angles between the fused ring system and the phenyl and methyl­benzoyl rings are 41.65 (11) and 66.30 (8)°, respectively. In the crystal, weak C—H⋯O hydrogen bonds and C—H⋯π inter­actions occur. One mol­ecule is linked to five adjacent ones through eight hydrogen bonds, forming a three-dimensional network.

Ejemplares similares