Ethyl 2-[6-(4-methyl­benzo­yl)-7-phenyl-2,3-di­hydro-1H-pyrrolizin-5-yl]-2-oxo­acetate

In the title compound, C(25)H(23)NO(4), the pyrrolizine ring is approximately planar with an r.m.s deviation from planarity of 0.0053 Å, while the fused di­hydro­pyrrolizine ring adopts an envelope conformation with the C atom connected to two CH(2) as the flap. The dihedral angles between the fused...

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Autores principales: Zhong, Jia-liang, Sun, Wen-xia, Zhang, Fu-li, Liu, Li-hong, Liu, He
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2013
Materias:
Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3885017/
https://www.ncbi.nlm.nih.gov/pubmed/24454192
http://dx.doi.org/10.1107/S1600536813029401
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author Zhong, Jia-liang
Sun, Wen-xia
Zhang, Fu-li
Liu, Li-hong
Liu, He
author_facet Zhong, Jia-liang
Sun, Wen-xia
Zhang, Fu-li
Liu, Li-hong
Liu, He
author_sort Zhong, Jia-liang
collection PubMed
description In the title compound, C(25)H(23)NO(4), the pyrrolizine ring is approximately planar with an r.m.s deviation from planarity of 0.0053 Å, while the fused di­hydro­pyrrolizine ring adopts an envelope conformation with the C atom connected to two CH(2) as the flap. The dihedral angles between the fused ring system and the phenyl and methyl­benzoyl rings are 41.65 (11) and 66.30 (8)°, respectively. In the crystal, weak C—H⋯O hydrogen bonds and C—H⋯π inter­actions occur. One mol­ecule is linked to five adjacent ones through eight hydrogen bonds, forming a three-dimensional network.
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spelling pubmed-38850172014-01-17 Ethyl 2-[6-(4-methyl­benzo­yl)-7-phenyl-2,3-di­hydro-1H-pyrrolizin-5-yl]-2-oxo­acetate Zhong, Jia-liang Sun, Wen-xia Zhang, Fu-li Liu, Li-hong Liu, He Acta Crystallogr Sect E Struct Rep Online Organic Papers In the title compound, C(25)H(23)NO(4), the pyrrolizine ring is approximately planar with an r.m.s deviation from planarity of 0.0053 Å, while the fused di­hydro­pyrrolizine ring adopts an envelope conformation with the C atom connected to two CH(2) as the flap. The dihedral angles between the fused ring system and the phenyl and methyl­benzoyl rings are 41.65 (11) and 66.30 (8)°, respectively. In the crystal, weak C—H⋯O hydrogen bonds and C—H⋯π inter­actions occur. One mol­ecule is linked to five adjacent ones through eight hydrogen bonds, forming a three-dimensional network. International Union of Crystallography 2013-11-06 /pmc/articles/PMC3885017/ /pubmed/24454192 http://dx.doi.org/10.1107/S1600536813029401 Text en © Zhong et al. 2013 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Organic Papers
Zhong, Jia-liang
Sun, Wen-xia
Zhang, Fu-li
Liu, Li-hong
Liu, He
Ethyl 2-[6-(4-methyl­benzo­yl)-7-phenyl-2,3-di­hydro-1H-pyrrolizin-5-yl]-2-oxo­acetate
title Ethyl 2-[6-(4-methyl­benzo­yl)-7-phenyl-2,3-di­hydro-1H-pyrrolizin-5-yl]-2-oxo­acetate
title_full Ethyl 2-[6-(4-methyl­benzo­yl)-7-phenyl-2,3-di­hydro-1H-pyrrolizin-5-yl]-2-oxo­acetate
title_fullStr Ethyl 2-[6-(4-methyl­benzo­yl)-7-phenyl-2,3-di­hydro-1H-pyrrolizin-5-yl]-2-oxo­acetate
title_full_unstemmed Ethyl 2-[6-(4-methyl­benzo­yl)-7-phenyl-2,3-di­hydro-1H-pyrrolizin-5-yl]-2-oxo­acetate
title_short Ethyl 2-[6-(4-methyl­benzo­yl)-7-phenyl-2,3-di­hydro-1H-pyrrolizin-5-yl]-2-oxo­acetate
title_sort ethyl 2-[6-(4-methyl­benzo­yl)-7-phenyl-2,3-di­hydro-1h-pyrrolizin-5-yl]-2-oxo­acetate
topic Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3885017/
https://www.ncbi.nlm.nih.gov/pubmed/24454192
http://dx.doi.org/10.1107/S1600536813029401
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AT liuhe ethyl264methylbenzoyl7phenyl23dihydro1hpyrrolizin5yl2oxoacetate

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