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N-Benzyl-2-hy­droxy­ethanaminium cyanurate

In the cation of the title compound C(9)H(14)ON(+)·C(3)H(2)O(3)N(3) (−), the benzyl­amine C—N bond subtends a dihedral angle of 78.3 (2)° with the phenyl ring. The cyanurate anion is in the usual keto-form and shows an r.m.s. deviation from planarity of 0.010 Å. In the crystal, the cyanurate anions...

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Autores principales: Contreras-Espejel, Carlos Abraham, García-Eleno, Marco A., Santacruz-Juárez, Ericka, Reyes-Martínez, Reyna, Morales-Morales, David
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2013
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3885023/
https://www.ncbi.nlm.nih.gov/pubmed/24454198
http://dx.doi.org/10.1107/S1600536813029383
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author Contreras-Espejel, Carlos Abraham
García-Eleno, Marco A.
Santacruz-Juárez, Ericka
Reyes-Martínez, Reyna
Morales-Morales, David
author_facet Contreras-Espejel, Carlos Abraham
García-Eleno, Marco A.
Santacruz-Juárez, Ericka
Reyes-Martínez, Reyna
Morales-Morales, David
author_sort Contreras-Espejel, Carlos Abraham
collection PubMed
description In the cation of the title compound C(9)H(14)ON(+)·C(3)H(2)O(3)N(3) (−), the benzyl­amine C—N bond subtends a dihedral angle of 78.3 (2)° with the phenyl ring. The cyanurate anion is in the usual keto-form and shows an r.m.s. deviation from planarity of 0.010 Å. In the crystal, the cyanurate anions form N—H⋯O hydrogen-bonded zigzag ribbons along [001]. These ribbons are crosslinked by the organocations via O—H⋯N and N—H⋯O hydrogen bonds, forming bilayers parallel to (010) which are held together along [010] by slipped π–π inter­actions between pairs of cyanurate anions [shortest contact distances C⋯C = 3.479 (2), O⋯N = 3.400 (2); centroid–centroid distance= 4.5946 (9) Å] and between cyanurate and phenyl rings [centroid–centroid distance = 3.7924 (12) Å, ring–ring angle = 11.99 (10)°].
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spelling pubmed-38850232014-01-17 N-Benzyl-2-hy­droxy­ethanaminium cyanurate Contreras-Espejel, Carlos Abraham García-Eleno, Marco A. Santacruz-Juárez, Ericka Reyes-Martínez, Reyna Morales-Morales, David Acta Crystallogr Sect E Struct Rep Online Organic Papers In the cation of the title compound C(9)H(14)ON(+)·C(3)H(2)O(3)N(3) (−), the benzyl­amine C—N bond subtends a dihedral angle of 78.3 (2)° with the phenyl ring. The cyanurate anion is in the usual keto-form and shows an r.m.s. deviation from planarity of 0.010 Å. In the crystal, the cyanurate anions form N—H⋯O hydrogen-bonded zigzag ribbons along [001]. These ribbons are crosslinked by the organocations via O—H⋯N and N—H⋯O hydrogen bonds, forming bilayers parallel to (010) which are held together along [010] by slipped π–π inter­actions between pairs of cyanurate anions [shortest contact distances C⋯C = 3.479 (2), O⋯N = 3.400 (2); centroid–centroid distance= 4.5946 (9) Å] and between cyanurate and phenyl rings [centroid–centroid distance = 3.7924 (12) Å, ring–ring angle = 11.99 (10)°]. International Union of Crystallography 2013-11-06 /pmc/articles/PMC3885023/ /pubmed/24454198 http://dx.doi.org/10.1107/S1600536813029383 Text en © Contreras-Espejel et al. 2013 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Organic Papers
Contreras-Espejel, Carlos Abraham
García-Eleno, Marco A.
Santacruz-Juárez, Ericka
Reyes-Martínez, Reyna
Morales-Morales, David
N-Benzyl-2-hy­droxy­ethanaminium cyanurate
title N-Benzyl-2-hy­droxy­ethanaminium cyanurate
title_full N-Benzyl-2-hy­droxy­ethanaminium cyanurate
title_fullStr N-Benzyl-2-hy­droxy­ethanaminium cyanurate
title_full_unstemmed N-Benzyl-2-hy­droxy­ethanaminium cyanurate
title_short N-Benzyl-2-hy­droxy­ethanaminium cyanurate
title_sort n-benzyl-2-hy­droxy­ethanaminium cyanurate
topic Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3885023/
https://www.ncbi.nlm.nih.gov/pubmed/24454198
http://dx.doi.org/10.1107/S1600536813029383
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