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N-Benzyl-2-hydroxyethanaminium cyanurate
In the cation of the title compound C(9)H(14)ON(+)·C(3)H(2)O(3)N(3) (−), the benzylamine C—N bond subtends a dihedral angle of 78.3 (2)° with the phenyl ring. The cyanurate anion is in the usual keto-form and shows an r.m.s. deviation from planarity of 0.010 Å. In the crystal, the cyanurate anions...
Autores principales: | , , , , |
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Formato: | Online Artículo Texto |
Lenguaje: | English |
Publicado: |
International Union of Crystallography
2013
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3885023/ https://www.ncbi.nlm.nih.gov/pubmed/24454198 http://dx.doi.org/10.1107/S1600536813029383 |
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author | Contreras-Espejel, Carlos Abraham García-Eleno, Marco A. Santacruz-Juárez, Ericka Reyes-Martínez, Reyna Morales-Morales, David |
author_facet | Contreras-Espejel, Carlos Abraham García-Eleno, Marco A. Santacruz-Juárez, Ericka Reyes-Martínez, Reyna Morales-Morales, David |
author_sort | Contreras-Espejel, Carlos Abraham |
collection | PubMed |
description | In the cation of the title compound C(9)H(14)ON(+)·C(3)H(2)O(3)N(3) (−), the benzylamine C—N bond subtends a dihedral angle of 78.3 (2)° with the phenyl ring. The cyanurate anion is in the usual keto-form and shows an r.m.s. deviation from planarity of 0.010 Å. In the crystal, the cyanurate anions form N—H⋯O hydrogen-bonded zigzag ribbons along [001]. These ribbons are crosslinked by the organocations via O—H⋯N and N—H⋯O hydrogen bonds, forming bilayers parallel to (010) which are held together along [010] by slipped π–π interactions between pairs of cyanurate anions [shortest contact distances C⋯C = 3.479 (2), O⋯N = 3.400 (2); centroid–centroid distance= 4.5946 (9) Å] and between cyanurate and phenyl rings [centroid–centroid distance = 3.7924 (12) Å, ring–ring angle = 11.99 (10)°]. |
format | Online Article Text |
id | pubmed-3885023 |
institution | National Center for Biotechnology Information |
language | English |
publishDate | 2013 |
publisher | International Union of Crystallography |
record_format | MEDLINE/PubMed |
spelling | pubmed-38850232014-01-17 N-Benzyl-2-hydroxyethanaminium cyanurate Contreras-Espejel, Carlos Abraham García-Eleno, Marco A. Santacruz-Juárez, Ericka Reyes-Martínez, Reyna Morales-Morales, David Acta Crystallogr Sect E Struct Rep Online Organic Papers In the cation of the title compound C(9)H(14)ON(+)·C(3)H(2)O(3)N(3) (−), the benzylamine C—N bond subtends a dihedral angle of 78.3 (2)° with the phenyl ring. The cyanurate anion is in the usual keto-form and shows an r.m.s. deviation from planarity of 0.010 Å. In the crystal, the cyanurate anions form N—H⋯O hydrogen-bonded zigzag ribbons along [001]. These ribbons are crosslinked by the organocations via O—H⋯N and N—H⋯O hydrogen bonds, forming bilayers parallel to (010) which are held together along [010] by slipped π–π interactions between pairs of cyanurate anions [shortest contact distances C⋯C = 3.479 (2), O⋯N = 3.400 (2); centroid–centroid distance= 4.5946 (9) Å] and between cyanurate and phenyl rings [centroid–centroid distance = 3.7924 (12) Å, ring–ring angle = 11.99 (10)°]. International Union of Crystallography 2013-11-06 /pmc/articles/PMC3885023/ /pubmed/24454198 http://dx.doi.org/10.1107/S1600536813029383 Text en © Contreras-Espejel et al. 2013 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited. |
spellingShingle | Organic Papers Contreras-Espejel, Carlos Abraham García-Eleno, Marco A. Santacruz-Juárez, Ericka Reyes-Martínez, Reyna Morales-Morales, David N-Benzyl-2-hydroxyethanaminium cyanurate |
title |
N-Benzyl-2-hydroxyethanaminium cyanurate |
title_full |
N-Benzyl-2-hydroxyethanaminium cyanurate |
title_fullStr |
N-Benzyl-2-hydroxyethanaminium cyanurate |
title_full_unstemmed |
N-Benzyl-2-hydroxyethanaminium cyanurate |
title_short |
N-Benzyl-2-hydroxyethanaminium cyanurate |
title_sort | n-benzyl-2-hydroxyethanaminium cyanurate |
topic | Organic Papers |
url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3885023/ https://www.ncbi.nlm.nih.gov/pubmed/24454198 http://dx.doi.org/10.1107/S1600536813029383 |
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