16-Methyl-11-(2-methyl­phen­yl)-14-phenyl-8,12-dioxa-14,15-di­aza­tetra­cyclo­[8.7.0.0(2,7).0(13,17)]hepta­deca-2(7),3,5,13(17),15-penta­ene-10-carbo­nitrile

In the title compound, C(28)H(23)N(3)O(2), the pyrazole ring makes a dihedral angle of 16.90 (6)° with the phenyl ring to which it is attached. Both di­hydro­pyran rings exhibit half-chair conformations. Intramolecular C—H⋯O interactions generate S(6) and S(8) ring motifs. In the crystal, weak C—H⋯O...

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Detalles Bibliográficos
Autores principales: Kanchanadevi, Jeevanandam, Anbalagan, Gopalakrishnan, Kannan, Damodharan, Bakthadoss, Manickam, Manivannan, Vadivelu
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2013
Materias:
Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3885026/
https://www.ncbi.nlm.nih.gov/pubmed/24454201
http://dx.doi.org/10.1107/S1600536813029905
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author Kanchanadevi, Jeevanandam
Anbalagan, Gopalakrishnan
Kannan, Damodharan
Bakthadoss, Manickam
Manivannan, Vadivelu
author_facet Kanchanadevi, Jeevanandam
Anbalagan, Gopalakrishnan
Kannan, Damodharan
Bakthadoss, Manickam
Manivannan, Vadivelu
author_sort Kanchanadevi, Jeevanandam
collection PubMed
description In the title compound, C(28)H(23)N(3)O(2), the pyrazole ring makes a dihedral angle of 16.90 (6)° with the phenyl ring to which it is attached. Both di­hydro­pyran rings exhibit half-chair conformations. Intramolecular C—H⋯O interactions generate S(6) and S(8) ring motifs. In the crystal, weak C—H⋯O and C—H⋯π interactions occur.
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spelling pubmed-38850262014-01-17 16-Methyl-11-(2-methyl­phen­yl)-14-phenyl-8,12-dioxa-14,15-di­aza­tetra­cyclo­[8.7.0.0(2,7).0(13,17)]hepta­deca-2(7),3,5,13(17),15-penta­ene-10-carbo­nitrile Kanchanadevi, Jeevanandam Anbalagan, Gopalakrishnan Kannan, Damodharan Bakthadoss, Manickam Manivannan, Vadivelu Acta Crystallogr Sect E Struct Rep Online Organic Papers In the title compound, C(28)H(23)N(3)O(2), the pyrazole ring makes a dihedral angle of 16.90 (6)° with the phenyl ring to which it is attached. Both di­hydro­pyran rings exhibit half-chair conformations. Intramolecular C—H⋯O interactions generate S(6) and S(8) ring motifs. In the crystal, weak C—H⋯O and C—H⋯π interactions occur. International Union of Crystallography 2013-11-06 /pmc/articles/PMC3885026/ /pubmed/24454201 http://dx.doi.org/10.1107/S1600536813029905 Text en © Kanchanadevi et al. 2013 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Organic Papers
Kanchanadevi, Jeevanandam
Anbalagan, Gopalakrishnan
Kannan, Damodharan
Bakthadoss, Manickam
Manivannan, Vadivelu
16-Methyl-11-(2-methyl­phen­yl)-14-phenyl-8,12-dioxa-14,15-di­aza­tetra­cyclo­[8.7.0.0(2,7).0(13,17)]hepta­deca-2(7),3,5,13(17),15-penta­ene-10-carbo­nitrile
title 16-Methyl-11-(2-methyl­phen­yl)-14-phenyl-8,12-dioxa-14,15-di­aza­tetra­cyclo­[8.7.0.0(2,7).0(13,17)]hepta­deca-2(7),3,5,13(17),15-penta­ene-10-carbo­nitrile
title_full 16-Methyl-11-(2-methyl­phen­yl)-14-phenyl-8,12-dioxa-14,15-di­aza­tetra­cyclo­[8.7.0.0(2,7).0(13,17)]hepta­deca-2(7),3,5,13(17),15-penta­ene-10-carbo­nitrile
title_fullStr 16-Methyl-11-(2-methyl­phen­yl)-14-phenyl-8,12-dioxa-14,15-di­aza­tetra­cyclo­[8.7.0.0(2,7).0(13,17)]hepta­deca-2(7),3,5,13(17),15-penta­ene-10-carbo­nitrile
title_full_unstemmed 16-Methyl-11-(2-methyl­phen­yl)-14-phenyl-8,12-dioxa-14,15-di­aza­tetra­cyclo­[8.7.0.0(2,7).0(13,17)]hepta­deca-2(7),3,5,13(17),15-penta­ene-10-carbo­nitrile
title_short 16-Methyl-11-(2-methyl­phen­yl)-14-phenyl-8,12-dioxa-14,15-di­aza­tetra­cyclo­[8.7.0.0(2,7).0(13,17)]hepta­deca-2(7),3,5,13(17),15-penta­ene-10-carbo­nitrile
title_sort 16-methyl-11-(2-methyl­phen­yl)-14-phenyl-8,12-dioxa-14,15-di­aza­tetra­cyclo­[8.7.0.0(2,7).0(13,17)]hepta­deca-2(7),3,5,13(17),15-penta­ene-10-carbo­nitrile
topic Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3885026/
https://www.ncbi.nlm.nih.gov/pubmed/24454201
http://dx.doi.org/10.1107/S1600536813029905
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