1-(3-Oxo-3-phenyl­prop­yl)piperidinium chloride

In the title salt, C(14)H(20)NO(+)·Cl(−), the piperidine ring adopts a chair conformation. In the crystal, the cations and anions are linked by classical N—H⋯Cl hydrogen bond and weak C—H⋯Cl and C—H⋯O hydrogen bonds; the C—H⋯O hydrogen bonds exhibit R (2) (2)(14) ring motifs while the C—H⋯Cl hydroge...

Descripción completa

Detalles Bibliográficos
Autores principales: Anuradha, Venkatramu, Madan Kumar, S., Siddaraju, B. P., Lokanath, N. K., Nagendra, P.
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2013
Materias:
Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3885028/
https://www.ncbi.nlm.nih.gov/pubmed/24454203
http://dx.doi.org/10.1107/S1600536813029887
Descripción
Sumario:In the title salt, C(14)H(20)NO(+)·Cl(−), the piperidine ring adopts a chair conformation. In the crystal, the cations and anions are linked by classical N—H⋯Cl hydrogen bond and weak C—H⋯Cl and C—H⋯O hydrogen bonds; the C—H⋯O hydrogen bonds exhibit R (2) (2)(14) ring motifs while the C—H⋯Cl hydrogen bonds link the mol­ecules into chains along the a-axis direction. π–π stacking is observed between parallel phenyl rings of adjacent cations, the centroid–centroid distance being 3.8164 (15) Å.

Ejemplares similares