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Bis{4-[(E)-2-(1H-indol-3-yl)ethenyl]-1-methylpyridinium} 4-chlorobenzenesulfonate nitrate
In the title mixed salt, 2C(16)H(15)N(2) (+)·C(6)H(4)ClO(3)S(−)·NO(3) (−), one of the cations shows whole molecule disorder over two sets of sites in a 0.711 (7):0.289 (7) ratio. The 4-chorobenzenesulfonate anion is also disordered over two orientations in a 0.503 (6):0.497 (6) ratio. The cations...
Autores principales: | , , , |
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Formato: | Online Artículo Texto |
Lenguaje: | English |
Publicado: |
International Union of Crystallography
2013
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3885032/ https://www.ncbi.nlm.nih.gov/pubmed/24454207 http://dx.doi.org/10.1107/S1600536813030080 |
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author | Fun, Hoong-Kun Quah, Ching Kheng Boonnak, Nawong Chantrapromma, Suchada |
author_facet | Fun, Hoong-Kun Quah, Ching Kheng Boonnak, Nawong Chantrapromma, Suchada |
author_sort | Fun, Hoong-Kun |
collection | PubMed |
description | In the title mixed salt, 2C(16)H(15)N(2) (+)·C(6)H(4)ClO(3)S(−)·NO(3) (−), one of the cations shows whole molecule disorder over two sets of sites in a 0.711 (7):0.289 (7) ratio. The 4-chorobenzenesulfonate anion is also disordered over two orientations in a 0.503 (6):0.497 (6) ratio. The cations are close to planar, the dihedral angles between the pyridinium and indole rings being 1.48 (3)° in the ordered cation, and 5.62 (3) and 2.45 (3)°, respectively, for the major and minor components of the disordered cation. In the crystal, the cations are stacked in an antiparallel manner approximately along the a-axis direction and linked with the anions via N—H⋯O hydrogen bonds and C—H⋯O interactions, generating a three-dimensional network. Weak C—H⋯π and π–π interactions [with centroid–centroid distances of 3.561 (2)–3.969 (7) Å] are also observed. |
format | Online Article Text |
id | pubmed-3885032 |
institution | National Center for Biotechnology Information |
language | English |
publishDate | 2013 |
publisher | International Union of Crystallography |
record_format | MEDLINE/PubMed |
spelling | pubmed-38850322014-01-17 Bis{4-[(E)-2-(1H-indol-3-yl)ethenyl]-1-methylpyridinium} 4-chlorobenzenesulfonate nitrate Fun, Hoong-Kun Quah, Ching Kheng Boonnak, Nawong Chantrapromma, Suchada Acta Crystallogr Sect E Struct Rep Online Organic Papers In the title mixed salt, 2C(16)H(15)N(2) (+)·C(6)H(4)ClO(3)S(−)·NO(3) (−), one of the cations shows whole molecule disorder over two sets of sites in a 0.711 (7):0.289 (7) ratio. The 4-chorobenzenesulfonate anion is also disordered over two orientations in a 0.503 (6):0.497 (6) ratio. The cations are close to planar, the dihedral angles between the pyridinium and indole rings being 1.48 (3)° in the ordered cation, and 5.62 (3) and 2.45 (3)°, respectively, for the major and minor components of the disordered cation. In the crystal, the cations are stacked in an antiparallel manner approximately along the a-axis direction and linked with the anions via N—H⋯O hydrogen bonds and C—H⋯O interactions, generating a three-dimensional network. Weak C—H⋯π and π–π interactions [with centroid–centroid distances of 3.561 (2)–3.969 (7) Å] are also observed. International Union of Crystallography 2013-11-09 /pmc/articles/PMC3885032/ /pubmed/24454207 http://dx.doi.org/10.1107/S1600536813030080 Text en © Fun et al. 2013 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited. |
spellingShingle | Organic Papers Fun, Hoong-Kun Quah, Ching Kheng Boonnak, Nawong Chantrapromma, Suchada Bis{4-[(E)-2-(1H-indol-3-yl)ethenyl]-1-methylpyridinium} 4-chlorobenzenesulfonate nitrate |
title | Bis{4-[(E)-2-(1H-indol-3-yl)ethenyl]-1-methylpyridinium} 4-chlorobenzenesulfonate nitrate |
title_full | Bis{4-[(E)-2-(1H-indol-3-yl)ethenyl]-1-methylpyridinium} 4-chlorobenzenesulfonate nitrate |
title_fullStr | Bis{4-[(E)-2-(1H-indol-3-yl)ethenyl]-1-methylpyridinium} 4-chlorobenzenesulfonate nitrate |
title_full_unstemmed | Bis{4-[(E)-2-(1H-indol-3-yl)ethenyl]-1-methylpyridinium} 4-chlorobenzenesulfonate nitrate |
title_short | Bis{4-[(E)-2-(1H-indol-3-yl)ethenyl]-1-methylpyridinium} 4-chlorobenzenesulfonate nitrate |
title_sort | bis{4-[(e)-2-(1h-indol-3-yl)ethenyl]-1-methylpyridinium} 4-chlorobenzenesulfonate nitrate |
topic | Organic Papers |
url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3885032/ https://www.ncbi.nlm.nih.gov/pubmed/24454207 http://dx.doi.org/10.1107/S1600536813030080 |
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