Ethyl 4-anilino-2-methyl-5-oxo-1-phenyl-2,5-di­hydro-1H-pyrrole-2-carboxyl­ate

In the title compound, C(20)H(20)N(2)O(3), the central 2,5-di­hydro-1H-pyrrole ring [r.m.s. deviation = 0.014 (1) Å] is oriented at dihedral angles of 77.81 (6) and 25.33 (6)°, respectively, to the attached phenyl ring and the aniline phenyl ring. An intra­molecular N—H⋯O hydrogen bond occurs. In th...

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Autores principales: Akkurt, Mehmet, Mohamed, Shaaban K., Elremaily, Mahmoud A. A., Santoyo-Gonzalez, Francisco, Albayati, Mustafa R.
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2013
Materias:
Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3885035/
https://www.ncbi.nlm.nih.gov/pubmed/24454210
http://dx.doi.org/10.1107/S1600536813030390
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author Akkurt, Mehmet
Mohamed, Shaaban K.
Elremaily, Mahmoud A. A.
Santoyo-Gonzalez, Francisco
Albayati, Mustafa R.
author_facet Akkurt, Mehmet
Mohamed, Shaaban K.
Elremaily, Mahmoud A. A.
Santoyo-Gonzalez, Francisco
Albayati, Mustafa R.
author_sort Akkurt, Mehmet
collection PubMed
description In the title compound, C(20)H(20)N(2)O(3), the central 2,5-di­hydro-1H-pyrrole ring [r.m.s. deviation = 0.014 (1) Å] is oriented at dihedral angles of 77.81 (6) and 25.33 (6)°, respectively, to the attached phenyl ring and the aniline phenyl ring. An intra­molecular N—H⋯O hydrogen bond occurs. In the crystal, mol­ecules are linked through pairs of N—H⋯O hydrogen bonds, forming inversion dimers with an R (2) (2)(10) ring motif. Two weak C—H⋯π inter­actions are also observed.
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spelling pubmed-38850352014-01-17 Ethyl 4-anilino-2-methyl-5-oxo-1-phenyl-2,5-di­hydro-1H-pyrrole-2-carboxyl­ate Akkurt, Mehmet Mohamed, Shaaban K. Elremaily, Mahmoud A. A. Santoyo-Gonzalez, Francisco Albayati, Mustafa R. Acta Crystallogr Sect E Struct Rep Online Organic Papers In the title compound, C(20)H(20)N(2)O(3), the central 2,5-di­hydro-1H-pyrrole ring [r.m.s. deviation = 0.014 (1) Å] is oriented at dihedral angles of 77.81 (6) and 25.33 (6)°, respectively, to the attached phenyl ring and the aniline phenyl ring. An intra­molecular N—H⋯O hydrogen bond occurs. In the crystal, mol­ecules are linked through pairs of N—H⋯O hydrogen bonds, forming inversion dimers with an R (2) (2)(10) ring motif. Two weak C—H⋯π inter­actions are also observed. International Union of Crystallography 2013-11-09 /pmc/articles/PMC3885035/ /pubmed/24454210 http://dx.doi.org/10.1107/S1600536813030390 Text en © Akkurt et al. 2013 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Organic Papers
Akkurt, Mehmet
Mohamed, Shaaban K.
Elremaily, Mahmoud A. A.
Santoyo-Gonzalez, Francisco
Albayati, Mustafa R.
Ethyl 4-anilino-2-methyl-5-oxo-1-phenyl-2,5-di­hydro-1H-pyrrole-2-carboxyl­ate
title Ethyl 4-anilino-2-methyl-5-oxo-1-phenyl-2,5-di­hydro-1H-pyrrole-2-carboxyl­ate
title_full Ethyl 4-anilino-2-methyl-5-oxo-1-phenyl-2,5-di­hydro-1H-pyrrole-2-carboxyl­ate
title_fullStr Ethyl 4-anilino-2-methyl-5-oxo-1-phenyl-2,5-di­hydro-1H-pyrrole-2-carboxyl­ate
title_full_unstemmed Ethyl 4-anilino-2-methyl-5-oxo-1-phenyl-2,5-di­hydro-1H-pyrrole-2-carboxyl­ate
title_short Ethyl 4-anilino-2-methyl-5-oxo-1-phenyl-2,5-di­hydro-1H-pyrrole-2-carboxyl­ate
title_sort ethyl 4-anilino-2-methyl-5-oxo-1-phenyl-2,5-di­hydro-1h-pyrrole-2-carboxyl­ate
topic Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3885035/
https://www.ncbi.nlm.nih.gov/pubmed/24454210
http://dx.doi.org/10.1107/S1600536813030390
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