5-[(1-Benzyl-1H-1,2,3-triazol-4-yl)meth­yl]-5H-dibenzo[b,f]azepine

In the title compound, C(24)H(20)N(4), the azepine ring adopts a boat conformation. The dihedral angle between the benzene rings fused to the azepine ring is 49.40 (9)°. The triazole ring makes a dihedral angle of 77.88 (9)° with the terminal phenyl ring. In the crystal, mol­ecules are linked via C—...

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Detalles Bibliográficos
Autores principales: Manjunath, B. C., Kumar, K. S. Vinay, Kumar, S. Madan, Sadashiva, M. P., Lokanath, N. K.
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2013
Materias:
Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3885037/
https://www.ncbi.nlm.nih.gov/pubmed/24454213
http://dx.doi.org/10.1107/S1600536813030547
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author Manjunath, B. C.
Kumar, K. S. Vinay
Kumar, S. Madan
Sadashiva, M. P.
Lokanath, N. K.
author_facet Manjunath, B. C.
Kumar, K. S. Vinay
Kumar, S. Madan
Sadashiva, M. P.
Lokanath, N. K.
author_sort Manjunath, B. C.
collection PubMed
description In the title compound, C(24)H(20)N(4), the azepine ring adopts a boat conformation. The dihedral angle between the benzene rings fused to the azepine ring is 49.40 (9)°. The triazole ring makes a dihedral angle of 77.88 (9)° with the terminal phenyl ring. In the crystal, mol­ecules are linked via C—H⋯π inter­actions and a parallel slipped π–π inter­action [centroid–centroid distance = 3.7324 (9), normal distance = 3.4060 (6) and slippage = 1.526 Å], forming a three-dimensional network.
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spelling pubmed-38850372014-01-17 5-[(1-Benzyl-1H-1,2,3-triazol-4-yl)meth­yl]-5H-dibenzo[b,f]azepine Manjunath, B. C. Kumar, K. S. Vinay Kumar, S. Madan Sadashiva, M. P. Lokanath, N. K. Acta Crystallogr Sect E Struct Rep Online Organic Papers In the title compound, C(24)H(20)N(4), the azepine ring adopts a boat conformation. The dihedral angle between the benzene rings fused to the azepine ring is 49.40 (9)°. The triazole ring makes a dihedral angle of 77.88 (9)° with the terminal phenyl ring. In the crystal, mol­ecules are linked via C—H⋯π inter­actions and a parallel slipped π–π inter­action [centroid–centroid distance = 3.7324 (9), normal distance = 3.4060 (6) and slippage = 1.526 Å], forming a three-dimensional network. International Union of Crystallography 2013-11-13 /pmc/articles/PMC3885037/ /pubmed/24454213 http://dx.doi.org/10.1107/S1600536813030547 Text en © Manjunath et al. 2013 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Organic Papers
Manjunath, B. C.
Kumar, K. S. Vinay
Kumar, S. Madan
Sadashiva, M. P.
Lokanath, N. K.
5-[(1-Benzyl-1H-1,2,3-triazol-4-yl)meth­yl]-5H-dibenzo[b,f]azepine
title 5-[(1-Benzyl-1H-1,2,3-triazol-4-yl)meth­yl]-5H-dibenzo[b,f]azepine
title_full 5-[(1-Benzyl-1H-1,2,3-triazol-4-yl)meth­yl]-5H-dibenzo[b,f]azepine
title_fullStr 5-[(1-Benzyl-1H-1,2,3-triazol-4-yl)meth­yl]-5H-dibenzo[b,f]azepine
title_full_unstemmed 5-[(1-Benzyl-1H-1,2,3-triazol-4-yl)meth­yl]-5H-dibenzo[b,f]azepine
title_short 5-[(1-Benzyl-1H-1,2,3-triazol-4-yl)meth­yl]-5H-dibenzo[b,f]azepine
title_sort 5-[(1-benzyl-1h-1,2,3-triazol-4-yl)meth­yl]-5h-dibenzo[b,f]azepine
topic Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3885037/
https://www.ncbi.nlm.nih.gov/pubmed/24454213
http://dx.doi.org/10.1107/S1600536813030547
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