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N′-Benzoyl-5-methyl-1,3-diphenyl-1H-pyrazole-4-carbohydrazide
In the title compound, C(24)H(20)N(4)O(2), the pyrazole ring makes dihedral angles of 47.57 (10)° and 30.56 (11)° with its N-bound and C-bound phenyl groups, respectively. The C—N—N—C group that links the two carbonyls has a torsion angle of 81.5 (2)°. The torsion angles between the carbonyl groups...
Autores principales: | , , , , , |
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Formato: | Online Artículo Texto |
Lenguaje: | English |
Publicado: |
International Union of Crystallography
2013
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3885042/ https://www.ncbi.nlm.nih.gov/pubmed/24454218 http://dx.doi.org/10.1107/S1600536813029528 |
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author | Chandra, Srikantamurthy, N. Kumar, Shamantha Doreswamy, B. H. Umesha, K. B. Mahendra, M. |
author_facet | Chandra, Srikantamurthy, N. Kumar, Shamantha Doreswamy, B. H. Umesha, K. B. Mahendra, M. |
author_sort | Chandra, |
collection | PubMed |
description | In the title compound, C(24)H(20)N(4)O(2), the pyrazole ring makes dihedral angles of 47.57 (10)° and 30.56 (11)° with its N-bound and C-bound phenyl groups, respectively. The C—N—N—C group that links the two carbonyls has a torsion angle of 81.5 (2)°. The torsion angles between the carbonyl groups and their adjacent pyrazole and phenyl rings are 125.89 (19) and 164.22 (17)°, respectively. In the crystal, pairs of molecules are linked by N—H⋯O hydrogen bonds into R (2) (2)(10) ring motifs, which in turn link to form chains that propagate parallel to the c-axis direction. |
format | Online Article Text |
id | pubmed-3885042 |
institution | National Center for Biotechnology Information |
language | English |
publishDate | 2013 |
publisher | International Union of Crystallography |
record_format | MEDLINE/PubMed |
spelling | pubmed-38850422014-01-17 N′-Benzoyl-5-methyl-1,3-diphenyl-1H-pyrazole-4-carbohydrazide Chandra, Srikantamurthy, N. Kumar, Shamantha Doreswamy, B. H. Umesha, K. B. Mahendra, M. Acta Crystallogr Sect E Struct Rep Online Organic Papers In the title compound, C(24)H(20)N(4)O(2), the pyrazole ring makes dihedral angles of 47.57 (10)° and 30.56 (11)° with its N-bound and C-bound phenyl groups, respectively. The C—N—N—C group that links the two carbonyls has a torsion angle of 81.5 (2)°. The torsion angles between the carbonyl groups and their adjacent pyrazole and phenyl rings are 125.89 (19) and 164.22 (17)°, respectively. In the crystal, pairs of molecules are linked by N—H⋯O hydrogen bonds into R (2) (2)(10) ring motifs, which in turn link to form chains that propagate parallel to the c-axis direction. International Union of Crystallography 2013-11-13 /pmc/articles/PMC3885042/ /pubmed/24454218 http://dx.doi.org/10.1107/S1600536813029528 Text en © Chandra et al. 2013 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited. |
spellingShingle | Organic Papers Chandra, Srikantamurthy, N. Kumar, Shamantha Doreswamy, B. H. Umesha, K. B. Mahendra, M. N′-Benzoyl-5-methyl-1,3-diphenyl-1H-pyrazole-4-carbohydrazide |
title |
N′-Benzoyl-5-methyl-1,3-diphenyl-1H-pyrazole-4-carbohydrazide |
title_full |
N′-Benzoyl-5-methyl-1,3-diphenyl-1H-pyrazole-4-carbohydrazide |
title_fullStr |
N′-Benzoyl-5-methyl-1,3-diphenyl-1H-pyrazole-4-carbohydrazide |
title_full_unstemmed |
N′-Benzoyl-5-methyl-1,3-diphenyl-1H-pyrazole-4-carbohydrazide |
title_short |
N′-Benzoyl-5-methyl-1,3-diphenyl-1H-pyrazole-4-carbohydrazide |
title_sort | n′-benzoyl-5-methyl-1,3-diphenyl-1h-pyrazole-4-carbohydrazide |
topic | Organic Papers |
url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3885042/ https://www.ncbi.nlm.nih.gov/pubmed/24454218 http://dx.doi.org/10.1107/S1600536813029528 |
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