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(3aR,8bR)-3a,8b-Dihy­droxy-2-methyl­sulfanyl-3-nitro-1-phenyl-1,8b-di­hydro­indeno[1,2-b]pyrrol-4(3aH)-one

In the title compound, C(18)H(14)N(2)O(5), the pyrrolidine ring adopts a shallow envelope conformation, with the C atom bearing the OH group (and remote from the N atom) displaced by 0.257 (2) Å from the other atoms. The cyclo­pentane ring has a twisted conformation about the C—C bond bearing one =O...

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Autores principales: Nagalakshmi, R. A., Suresh, J., Jeyachandran, V., Kumar, R. Ranjith, Lakshman, P. L. Nilantha
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2013
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3885043/
https://www.ncbi.nlm.nih.gov/pubmed/24454219
http://dx.doi.org/10.1107/S1600536813029577
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author Nagalakshmi, R. A.
Suresh, J.
Jeyachandran, V.
Kumar, R. Ranjith
Lakshman, P. L. Nilantha
author_facet Nagalakshmi, R. A.
Suresh, J.
Jeyachandran, V.
Kumar, R. Ranjith
Lakshman, P. L. Nilantha
author_sort Nagalakshmi, R. A.
collection PubMed
description In the title compound, C(18)H(14)N(2)O(5), the pyrrolidine ring adopts a shallow envelope conformation, with the C atom bearing the OH group (and remote from the N atom) displaced by 0.257 (2) Å from the other atoms. The cyclo­pentane ring has a twisted conformation about the C—C bond bearing one =O and one —OH grouping. The dihedral angle between the five-membered rings (all atoms) is 65.54 (9)° and the OH groups lie to the same side of the ring-junction. The mol­ecular structure features a weak intra­molecular O—H⋯O bond and a possible C—H⋯π inter­action. In the crystal, the mol­ecules are linked into [010] chains by O—H⋯O hydrogen bonds. Weak C—H⋯O bonds connect the chains into (100) sheets.
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spelling pubmed-38850432014-01-17 (3aR,8bR)-3a,8b-Dihy­droxy-2-methyl­sulfanyl-3-nitro-1-phenyl-1,8b-di­hydro­indeno[1,2-b]pyrrol-4(3aH)-one Nagalakshmi, R. A. Suresh, J. Jeyachandran, V. Kumar, R. Ranjith Lakshman, P. L. Nilantha Acta Crystallogr Sect E Struct Rep Online Organic Papers In the title compound, C(18)H(14)N(2)O(5), the pyrrolidine ring adopts a shallow envelope conformation, with the C atom bearing the OH group (and remote from the N atom) displaced by 0.257 (2) Å from the other atoms. The cyclo­pentane ring has a twisted conformation about the C—C bond bearing one =O and one —OH grouping. The dihedral angle between the five-membered rings (all atoms) is 65.54 (9)° and the OH groups lie to the same side of the ring-junction. The mol­ecular structure features a weak intra­molecular O—H⋯O bond and a possible C—H⋯π inter­action. In the crystal, the mol­ecules are linked into [010] chains by O—H⋯O hydrogen bonds. Weak C—H⋯O bonds connect the chains into (100) sheets. International Union of Crystallography 2013-11-13 /pmc/articles/PMC3885043/ /pubmed/24454219 http://dx.doi.org/10.1107/S1600536813029577 Text en © Nagalakshmi et al. 2013 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Organic Papers
Nagalakshmi, R. A.
Suresh, J.
Jeyachandran, V.
Kumar, R. Ranjith
Lakshman, P. L. Nilantha
(3aR,8bR)-3a,8b-Dihy­droxy-2-methyl­sulfanyl-3-nitro-1-phenyl-1,8b-di­hydro­indeno[1,2-b]pyrrol-4(3aH)-one
title (3aR,8bR)-3a,8b-Dihy­droxy-2-methyl­sulfanyl-3-nitro-1-phenyl-1,8b-di­hydro­indeno[1,2-b]pyrrol-4(3aH)-one
title_full (3aR,8bR)-3a,8b-Dihy­droxy-2-methyl­sulfanyl-3-nitro-1-phenyl-1,8b-di­hydro­indeno[1,2-b]pyrrol-4(3aH)-one
title_fullStr (3aR,8bR)-3a,8b-Dihy­droxy-2-methyl­sulfanyl-3-nitro-1-phenyl-1,8b-di­hydro­indeno[1,2-b]pyrrol-4(3aH)-one
title_full_unstemmed (3aR,8bR)-3a,8b-Dihy­droxy-2-methyl­sulfanyl-3-nitro-1-phenyl-1,8b-di­hydro­indeno[1,2-b]pyrrol-4(3aH)-one
title_short (3aR,8bR)-3a,8b-Dihy­droxy-2-methyl­sulfanyl-3-nitro-1-phenyl-1,8b-di­hydro­indeno[1,2-b]pyrrol-4(3aH)-one
title_sort (3ar,8br)-3a,8b-dihy­droxy-2-methyl­sulfanyl-3-nitro-1-phenyl-1,8b-di­hydro­indeno[1,2-b]pyrrol-4(3ah)-one
topic Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3885043/
https://www.ncbi.nlm.nih.gov/pubmed/24454219
http://dx.doi.org/10.1107/S1600536813029577
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