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(3aR,8bR)-3a,8b-Dihydroxy-2-methylsulfanyl-3-nitro-1-phenyl-1,8b-dihydroindeno[1,2-b]pyrrol-4(3aH)-one
In the title compound, C(18)H(14)N(2)O(5), the pyrrolidine ring adopts a shallow envelope conformation, with the C atom bearing the OH group (and remote from the N atom) displaced by 0.257 (2) Å from the other atoms. The cyclopentane ring has a twisted conformation about the C—C bond bearing one =O...
Autores principales: | , , , , |
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Formato: | Online Artículo Texto |
Lenguaje: | English |
Publicado: |
International Union of Crystallography
2013
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3885043/ https://www.ncbi.nlm.nih.gov/pubmed/24454219 http://dx.doi.org/10.1107/S1600536813029577 |
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author | Nagalakshmi, R. A. Suresh, J. Jeyachandran, V. Kumar, R. Ranjith Lakshman, P. L. Nilantha |
author_facet | Nagalakshmi, R. A. Suresh, J. Jeyachandran, V. Kumar, R. Ranjith Lakshman, P. L. Nilantha |
author_sort | Nagalakshmi, R. A. |
collection | PubMed |
description | In the title compound, C(18)H(14)N(2)O(5), the pyrrolidine ring adopts a shallow envelope conformation, with the C atom bearing the OH group (and remote from the N atom) displaced by 0.257 (2) Å from the other atoms. The cyclopentane ring has a twisted conformation about the C—C bond bearing one =O and one —OH grouping. The dihedral angle between the five-membered rings (all atoms) is 65.54 (9)° and the OH groups lie to the same side of the ring-junction. The molecular structure features a weak intramolecular O—H⋯O bond and a possible C—H⋯π interaction. In the crystal, the molecules are linked into [010] chains by O—H⋯O hydrogen bonds. Weak C—H⋯O bonds connect the chains into (100) sheets. |
format | Online Article Text |
id | pubmed-3885043 |
institution | National Center for Biotechnology Information |
language | English |
publishDate | 2013 |
publisher | International Union of Crystallography |
record_format | MEDLINE/PubMed |
spelling | pubmed-38850432014-01-17 (3aR,8bR)-3a,8b-Dihydroxy-2-methylsulfanyl-3-nitro-1-phenyl-1,8b-dihydroindeno[1,2-b]pyrrol-4(3aH)-one Nagalakshmi, R. A. Suresh, J. Jeyachandran, V. Kumar, R. Ranjith Lakshman, P. L. Nilantha Acta Crystallogr Sect E Struct Rep Online Organic Papers In the title compound, C(18)H(14)N(2)O(5), the pyrrolidine ring adopts a shallow envelope conformation, with the C atom bearing the OH group (and remote from the N atom) displaced by 0.257 (2) Å from the other atoms. The cyclopentane ring has a twisted conformation about the C—C bond bearing one =O and one —OH grouping. The dihedral angle between the five-membered rings (all atoms) is 65.54 (9)° and the OH groups lie to the same side of the ring-junction. The molecular structure features a weak intramolecular O—H⋯O bond and a possible C—H⋯π interaction. In the crystal, the molecules are linked into [010] chains by O—H⋯O hydrogen bonds. Weak C—H⋯O bonds connect the chains into (100) sheets. International Union of Crystallography 2013-11-13 /pmc/articles/PMC3885043/ /pubmed/24454219 http://dx.doi.org/10.1107/S1600536813029577 Text en © Nagalakshmi et al. 2013 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited. |
spellingShingle | Organic Papers Nagalakshmi, R. A. Suresh, J. Jeyachandran, V. Kumar, R. Ranjith Lakshman, P. L. Nilantha (3aR,8bR)-3a,8b-Dihydroxy-2-methylsulfanyl-3-nitro-1-phenyl-1,8b-dihydroindeno[1,2-b]pyrrol-4(3aH)-one |
title | (3aR,8bR)-3a,8b-Dihydroxy-2-methylsulfanyl-3-nitro-1-phenyl-1,8b-dihydroindeno[1,2-b]pyrrol-4(3aH)-one |
title_full | (3aR,8bR)-3a,8b-Dihydroxy-2-methylsulfanyl-3-nitro-1-phenyl-1,8b-dihydroindeno[1,2-b]pyrrol-4(3aH)-one |
title_fullStr | (3aR,8bR)-3a,8b-Dihydroxy-2-methylsulfanyl-3-nitro-1-phenyl-1,8b-dihydroindeno[1,2-b]pyrrol-4(3aH)-one |
title_full_unstemmed | (3aR,8bR)-3a,8b-Dihydroxy-2-methylsulfanyl-3-nitro-1-phenyl-1,8b-dihydroindeno[1,2-b]pyrrol-4(3aH)-one |
title_short | (3aR,8bR)-3a,8b-Dihydroxy-2-methylsulfanyl-3-nitro-1-phenyl-1,8b-dihydroindeno[1,2-b]pyrrol-4(3aH)-one |
title_sort | (3ar,8br)-3a,8b-dihydroxy-2-methylsulfanyl-3-nitro-1-phenyl-1,8b-dihydroindeno[1,2-b]pyrrol-4(3ah)-one |
topic | Organic Papers |
url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3885043/ https://www.ncbi.nlm.nih.gov/pubmed/24454219 http://dx.doi.org/10.1107/S1600536813029577 |
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