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2-N-Benzyl-2,6-dide­oxy-2,6-imino-3,4-O-iso­propyl­idene-d-allono­nitrile

X-ray crystallography firmly established the relative stereochemistry of the title compound, C(16)H(20)N(2)O(3). The acetonide ring adopts an envelope conformation with one of the O atoms as the flap and the piperidine ring adopts a slightly twisted boat conformation. The absolute configuration was...

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Detalles Bibliográficos
Autores principales: Ayers, Benjamin J., Jenkinson, Sarah F., Fleet, George W. J., Thompson, Amber L.
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2013
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3885044/
https://www.ncbi.nlm.nih.gov/pubmed/24454220
http://dx.doi.org/10.1107/S1600536813030584
Descripción
Sumario:X-ray crystallography firmly established the relative stereochemistry of the title compound, C(16)H(20)N(2)O(3). The acetonide ring adopts an envelope conformation with one of the O atoms as the flap and the piperidine ring adopts a slightly twisted boat conformation. The absolute configuration was determined by use of d-ribose as the starting material. The compound exists as O—H⋯O hydrogen-bonded chains of mol­ecules running parallel to the b axis.