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(E)-2-[2-(4-Carboxyphenyl)ethenyl]-8-hydroxyquinolin-1-ium chloride ethanol monosolvate
In the title compound, C(18)H(14)NO(3) (+)·Cl(−)·CH(3)CH(2)OH, the dihedral angle formed by the mean planes of the quinolinium and benzene rings is 3.4 (1)°, while the carboxy substituent is tilted at an angle of 4.8 (1)° with respect to the benzene ring. There is a short N—H⋯O contact in the catio...
Autores principales: | , , |
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Formato: | Online Artículo Texto |
Lenguaje: | English |
Publicado: |
International Union of Crystallography
2013
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3885045/ https://www.ncbi.nlm.nih.gov/pubmed/24454221 http://dx.doi.org/10.1107/S1600536813030274 |
Sumario: | In the title compound, C(18)H(14)NO(3) (+)·Cl(−)·CH(3)CH(2)OH, the dihedral angle formed by the mean planes of the quinolinium and benzene rings is 3.4 (1)°, while the carboxy substituent is tilted at an angle of 4.8 (1)° with respect to the benzene ring. There is a short N—H⋯O contact in the cation. In the crystal, due to the planar molecular geometry, two-dimensional aggregates are formed parallel to (221) via C—H⋯O, C—H⋯Cl, O—H⋯Cl and N—H⋯Cl hydrogen bonds. Interlayer association is accomplished by O—H(ethanol)⋯Cl and O—H⋯O(ethanol) hydrogen bonds and π–π stacking interactions [centroid–centroid distances vary from 3.6477 (12) to 3.8381 (11) Å]. A supramolecular three-dimensional architecture results from a stacked arrangement of layers comprising the ionic and hydrogen-bonded components. |
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