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3-[1-(4-Bromophenyl)ethoxy]-2,2,5-trimethyl-4-phenyl-3-azahexane
The title compound, C(22)H(30)BrNO, is an alkoxyamine compound, an effective initiator in nitroxide-mediated free radical polymerization. It was prepared as a mixture of two diasteromers; the crystal for the X-ray analysis showed one of these as a pair of R,S and S,R enantiomers. The tert-butyl a...
Autores principales: | , , , , , |
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Formato: | Online Artículo Texto |
Lenguaje: | English |
Publicado: |
International Union of Crystallography
2013
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3885056/ https://www.ncbi.nlm.nih.gov/pubmed/24454232 http://dx.doi.org/10.1107/S1600536813029966 |
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author | Pitliya, Praveen Butcher, Ray J. Karim, A. Hudrlik, Paul F. Hudrlik, Anne M. Raghavan, D. |
author_facet | Pitliya, Praveen Butcher, Ray J. Karim, A. Hudrlik, Paul F. Hudrlik, Anne M. Raghavan, D. |
author_sort | Pitliya, Praveen |
collection | PubMed |
description | The title compound, C(22)H(30)BrNO, is an alkoxyamine compound, an effective initiator in nitroxide-mediated free radical polymerization. It was prepared as a mixture of two diasteromers; the crystal for the X-ray analysis showed one of these as a pair of R,S and S,R enantiomers. The tert-butyl and isopropyl groups are in an almost anti conformation in the crystal [C—N—C—C torsion angle = −168.8 (1)°], and the methyl group of the ethoxy group is in an approximate anti relationship to the tert-butyl group. The dihedral angle between the phenyl and benzene rings is 33.12 (7)°. The Br atom is disordered over two positions, with occupancies of 0.9139 (16) and 0.0861 (16). In the crystal, weak C—H⋯Br contacts link the molecules into chains along [-110]. |
format | Online Article Text |
id | pubmed-3885056 |
institution | National Center for Biotechnology Information |
language | English |
publishDate | 2013 |
publisher | International Union of Crystallography |
record_format | MEDLINE/PubMed |
spelling | pubmed-38850562014-01-17 3-[1-(4-Bromophenyl)ethoxy]-2,2,5-trimethyl-4-phenyl-3-azahexane Pitliya, Praveen Butcher, Ray J. Karim, A. Hudrlik, Paul F. Hudrlik, Anne M. Raghavan, D. Acta Crystallogr Sect E Struct Rep Online Organic Papers The title compound, C(22)H(30)BrNO, is an alkoxyamine compound, an effective initiator in nitroxide-mediated free radical polymerization. It was prepared as a mixture of two diasteromers; the crystal for the X-ray analysis showed one of these as a pair of R,S and S,R enantiomers. The tert-butyl and isopropyl groups are in an almost anti conformation in the crystal [C—N—C—C torsion angle = −168.8 (1)°], and the methyl group of the ethoxy group is in an approximate anti relationship to the tert-butyl group. The dihedral angle between the phenyl and benzene rings is 33.12 (7)°. The Br atom is disordered over two positions, with occupancies of 0.9139 (16) and 0.0861 (16). In the crystal, weak C—H⋯Br contacts link the molecules into chains along [-110]. International Union of Crystallography 2013-11-20 /pmc/articles/PMC3885056/ /pubmed/24454232 http://dx.doi.org/10.1107/S1600536813029966 Text en © Pitliya et al. 2013 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited. |
spellingShingle | Organic Papers Pitliya, Praveen Butcher, Ray J. Karim, A. Hudrlik, Paul F. Hudrlik, Anne M. Raghavan, D. 3-[1-(4-Bromophenyl)ethoxy]-2,2,5-trimethyl-4-phenyl-3-azahexane |
title | 3-[1-(4-Bromophenyl)ethoxy]-2,2,5-trimethyl-4-phenyl-3-azahexane |
title_full | 3-[1-(4-Bromophenyl)ethoxy]-2,2,5-trimethyl-4-phenyl-3-azahexane |
title_fullStr | 3-[1-(4-Bromophenyl)ethoxy]-2,2,5-trimethyl-4-phenyl-3-azahexane |
title_full_unstemmed | 3-[1-(4-Bromophenyl)ethoxy]-2,2,5-trimethyl-4-phenyl-3-azahexane |
title_short | 3-[1-(4-Bromophenyl)ethoxy]-2,2,5-trimethyl-4-phenyl-3-azahexane |
title_sort | 3-[1-(4-bromophenyl)ethoxy]-2,2,5-trimethyl-4-phenyl-3-azahexane |
topic | Organic Papers |
url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3885056/ https://www.ncbi.nlm.nih.gov/pubmed/24454232 http://dx.doi.org/10.1107/S1600536813029966 |
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