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6-(4-Aminophenyl)-2-methoxy-4-phenylnicotinonitrile
In the structure of the title nicotinonitrile derivative, C(19)H(15)N(3)O, the pyridine ring makes dihedral angles of 11.50 (7) and 43.36 (8)° with the 4-aminophenyl and phenyl rings, respectively, and the dihedral angle between the phenyl rings is 36.28°. In the crystal, molecules are linked by...
Autores principales: | , , , |
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Formato: | Online Artículo Texto |
Lenguaje: | English |
Publicado: |
International Union of Crystallography
2013
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3885069/ https://www.ncbi.nlm.nih.gov/pubmed/24454245 http://dx.doi.org/10.1107/S1600536813031437 |
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author | Suwunwong, Thitipone Chantrapromma, Suchada Quah, Ching Kheng Fun, Hoong-Kun |
author_facet | Suwunwong, Thitipone Chantrapromma, Suchada Quah, Ching Kheng Fun, Hoong-Kun |
author_sort | Suwunwong, Thitipone |
collection | PubMed |
description | In the structure of the title nicotinonitrile derivative, C(19)H(15)N(3)O, the pyridine ring makes dihedral angles of 11.50 (7) and 43.36 (8)° with the 4-aminophenyl and phenyl rings, respectively, and the dihedral angle between the phenyl rings is 36.28°. In the crystal, molecules are linked by N—H⋯N hydrogen bonds into wave-like sheets parallel to (10-2). These sheets are stacked by π–π interactions between the 4-aminophenyl rings of adjacent sheets, with centroid–centroid distances of 3.7499 (9) Å. C—H⋯π interactions are also present. |
format | Online Article Text |
id | pubmed-3885069 |
institution | National Center for Biotechnology Information |
language | English |
publishDate | 2013 |
publisher | International Union of Crystallography |
record_format | MEDLINE/PubMed |
spelling | pubmed-38850692014-01-17 6-(4-Aminophenyl)-2-methoxy-4-phenylnicotinonitrile Suwunwong, Thitipone Chantrapromma, Suchada Quah, Ching Kheng Fun, Hoong-Kun Acta Crystallogr Sect E Struct Rep Online Organic Papers In the structure of the title nicotinonitrile derivative, C(19)H(15)N(3)O, the pyridine ring makes dihedral angles of 11.50 (7) and 43.36 (8)° with the 4-aminophenyl and phenyl rings, respectively, and the dihedral angle between the phenyl rings is 36.28°. In the crystal, molecules are linked by N—H⋯N hydrogen bonds into wave-like sheets parallel to (10-2). These sheets are stacked by π–π interactions between the 4-aminophenyl rings of adjacent sheets, with centroid–centroid distances of 3.7499 (9) Å. C—H⋯π interactions are also present. International Union of Crystallography 2013-11-23 /pmc/articles/PMC3885069/ /pubmed/24454245 http://dx.doi.org/10.1107/S1600536813031437 Text en © Suwunwong et al. 2013 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited. |
spellingShingle | Organic Papers Suwunwong, Thitipone Chantrapromma, Suchada Quah, Ching Kheng Fun, Hoong-Kun 6-(4-Aminophenyl)-2-methoxy-4-phenylnicotinonitrile |
title | 6-(4-Aminophenyl)-2-methoxy-4-phenylnicotinonitrile |
title_full | 6-(4-Aminophenyl)-2-methoxy-4-phenylnicotinonitrile |
title_fullStr | 6-(4-Aminophenyl)-2-methoxy-4-phenylnicotinonitrile |
title_full_unstemmed | 6-(4-Aminophenyl)-2-methoxy-4-phenylnicotinonitrile |
title_short | 6-(4-Aminophenyl)-2-methoxy-4-phenylnicotinonitrile |
title_sort | 6-(4-aminophenyl)-2-methoxy-4-phenylnicotinonitrile |
topic | Organic Papers |
url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3885069/ https://www.ncbi.nlm.nih.gov/pubmed/24454245 http://dx.doi.org/10.1107/S1600536813031437 |
work_keys_str_mv | AT suwunwongthitipone 64aminophenyl2methoxy4phenylnicotinonitrile AT chantraprommasuchada 64aminophenyl2methoxy4phenylnicotinonitrile AT quahchingkheng 64aminophenyl2methoxy4phenylnicotinonitrile AT funhoongkun 64aminophenyl2methoxy4phenylnicotinonitrile |