Diethyl [4-(2,2′:6′,2′′-terpyridine-4′-yl)phen­yl]phospho­nate

The title compound, C(25)H(24)N(3)O(3)P, was obtained by catalytic phospho­nation of 4′-(4-bromphen­yl)-2,2′:6′,2′′-terpyridine. The terpyridine moiety is nearly planar, the dihedral angles between the central and the outer rings being 4.06 (9) and 5.39 (9)°. The N atoms in the two pyridine rings ar...

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Detalles Bibliográficos
Autores principales: Chyba, Jan, Necas, Marek, Pinkas, Jiri
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2013
Materias:
Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3885073/
https://www.ncbi.nlm.nih.gov/pubmed/24454249
http://dx.doi.org/10.1107/S1600536813031541
Descripción
Sumario:The title compound, C(25)H(24)N(3)O(3)P, was obtained by catalytic phospho­nation of 4′-(4-bromphen­yl)-2,2′:6′,2′′-terpyridine. The terpyridine moiety is nearly planar, the dihedral angles between the central and the outer rings being 4.06 (9) and 5.39 (9)°. The N atoms in the two pyridine rings are oriented nearly anti­periplanar to that of the central ring. The benzene ring is rotated out of the plane of the central ring of the terpyridine unit by 34.65 (6)°.

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