Diethyl [4-(2,2′:6′,2′′-terpyridine-4′-yl)phen­yl]phospho­nate

The title compound, C(25)H(24)N(3)O(3)P, was obtained by catalytic phospho­nation of 4′-(4-bromphen­yl)-2,2′:6′,2′′-terpyridine. The terpyridine moiety is nearly planar, the dihedral angles between the central and the outer rings being 4.06 (9) and 5.39 (9)°. The N atoms in the two pyridine rings ar...

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Detalles Bibliográficos
Autores principales: Chyba, Jan, Necas, Marek, Pinkas, Jiri
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2013
Materias:
Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3885073/
https://www.ncbi.nlm.nih.gov/pubmed/24454249
http://dx.doi.org/10.1107/S1600536813031541
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author Chyba, Jan
Necas, Marek
Pinkas, Jiri
author_facet Chyba, Jan
Necas, Marek
Pinkas, Jiri
author_sort Chyba, Jan
collection PubMed
description The title compound, C(25)H(24)N(3)O(3)P, was obtained by catalytic phospho­nation of 4′-(4-bromphen­yl)-2,2′:6′,2′′-terpyridine. The terpyridine moiety is nearly planar, the dihedral angles between the central and the outer rings being 4.06 (9) and 5.39 (9)°. The N atoms in the two pyridine rings are oriented nearly anti­periplanar to that of the central ring. The benzene ring is rotated out of the plane of the central ring of the terpyridine unit by 34.65 (6)°.
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spelling pubmed-38850732014-01-17 Diethyl [4-(2,2′:6′,2′′-terpyridine-4′-yl)phen­yl]phospho­nate Chyba, Jan Necas, Marek Pinkas, Jiri Acta Crystallogr Sect E Struct Rep Online Organic Papers The title compound, C(25)H(24)N(3)O(3)P, was obtained by catalytic phospho­nation of 4′-(4-bromphen­yl)-2,2′:6′,2′′-terpyridine. The terpyridine moiety is nearly planar, the dihedral angles between the central and the outer rings being 4.06 (9) and 5.39 (9)°. The N atoms in the two pyridine rings are oriented nearly anti­periplanar to that of the central ring. The benzene ring is rotated out of the plane of the central ring of the terpyridine unit by 34.65 (6)°. International Union of Crystallography 2013-11-27 /pmc/articles/PMC3885073/ /pubmed/24454249 http://dx.doi.org/10.1107/S1600536813031541 Text en © Chyba et al. 2013 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Organic Papers
Chyba, Jan
Necas, Marek
Pinkas, Jiri
Diethyl [4-(2,2′:6′,2′′-terpyridine-4′-yl)phen­yl]phospho­nate
title Diethyl [4-(2,2′:6′,2′′-terpyridine-4′-yl)phen­yl]phospho­nate
title_full Diethyl [4-(2,2′:6′,2′′-terpyridine-4′-yl)phen­yl]phospho­nate
title_fullStr Diethyl [4-(2,2′:6′,2′′-terpyridine-4′-yl)phen­yl]phospho­nate
title_full_unstemmed Diethyl [4-(2,2′:6′,2′′-terpyridine-4′-yl)phen­yl]phospho­nate
title_short Diethyl [4-(2,2′:6′,2′′-terpyridine-4′-yl)phen­yl]phospho­nate
title_sort diethyl [4-(2,2′:6′,2′′-terpyridine-4′-yl)phen­yl]phospho­nate
topic Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3885073/
https://www.ncbi.nlm.nih.gov/pubmed/24454249
http://dx.doi.org/10.1107/S1600536813031541
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AT necasmarek diethyl42262terpyridine4ylphenylphosphonate
AT pinkasjiri diethyl42262terpyridine4ylphenylphosphonate

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