5-[(2-Methyl-4-nitro-1H-imidazol-1-yl)meth­yl]-1,3,4-thia­diazol-2-amine

In the title compound, C(7)H(8)N(6)O(2)S, the dihedral angle between the imidazole and thia­diazole rings is 70.86 (15)°. In the crystal, mol­ecules are linked into [10-1] chains by N—H⋯N hydrogen bonds, which incorporate centrosymmetric R (2) (2)(8) and R (2) (2)(18) loops. The chains are linked by...

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Autores principales: Usha, M. K., Madan Kumar, S., Vidyashree Jois, H. S., Kalluraya, B., Lokanath, N. K., Revannasiddaiah, D.
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2013
Materias:
Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3885074/
https://www.ncbi.nlm.nih.gov/pubmed/24454250
http://dx.doi.org/10.1107/S1600536813030821
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author Usha, M. K.
Madan Kumar, S.
Vidyashree Jois, H. S.
Kalluraya, B.
Lokanath, N. K.
Revannasiddaiah, D.
author_facet Usha, M. K.
Madan Kumar, S.
Vidyashree Jois, H. S.
Kalluraya, B.
Lokanath, N. K.
Revannasiddaiah, D.
author_sort Usha, M. K.
collection PubMed
description In the title compound, C(7)H(8)N(6)O(2)S, the dihedral angle between the imidazole and thia­diazole rings is 70.86 (15)°. In the crystal, mol­ecules are linked into [10-1] chains by N—H⋯N hydrogen bonds, which incorporate centrosymmetric R (2) (2)(8) and R (2) (2)(18) loops. The chains are linked by C—H⋯O and C—H⋯N inter­actions, generating a three-dimensional network. Very weak π–π stacking [centroid–centroid distance = 3.901 (17) Å] is also observed.
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spelling pubmed-38850742014-01-17 5-[(2-Methyl-4-nitro-1H-imidazol-1-yl)meth­yl]-1,3,4-thia­diazol-2-amine Usha, M. K. Madan Kumar, S. Vidyashree Jois, H. S. Kalluraya, B. Lokanath, N. K. Revannasiddaiah, D. Acta Crystallogr Sect E Struct Rep Online Organic Papers In the title compound, C(7)H(8)N(6)O(2)S, the dihedral angle between the imidazole and thia­diazole rings is 70.86 (15)°. In the crystal, mol­ecules are linked into [10-1] chains by N—H⋯N hydrogen bonds, which incorporate centrosymmetric R (2) (2)(8) and R (2) (2)(18) loops. The chains are linked by C—H⋯O and C—H⋯N inter­actions, generating a three-dimensional network. Very weak π–π stacking [centroid–centroid distance = 3.901 (17) Å] is also observed. International Union of Crystallography 2013-11-27 /pmc/articles/PMC3885074/ /pubmed/24454250 http://dx.doi.org/10.1107/S1600536813030821 Text en © Usha et al. 2013 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Organic Papers
Usha, M. K.
Madan Kumar, S.
Vidyashree Jois, H. S.
Kalluraya, B.
Lokanath, N. K.
Revannasiddaiah, D.
5-[(2-Methyl-4-nitro-1H-imidazol-1-yl)meth­yl]-1,3,4-thia­diazol-2-amine
title 5-[(2-Methyl-4-nitro-1H-imidazol-1-yl)meth­yl]-1,3,4-thia­diazol-2-amine
title_full 5-[(2-Methyl-4-nitro-1H-imidazol-1-yl)meth­yl]-1,3,4-thia­diazol-2-amine
title_fullStr 5-[(2-Methyl-4-nitro-1H-imidazol-1-yl)meth­yl]-1,3,4-thia­diazol-2-amine
title_full_unstemmed 5-[(2-Methyl-4-nitro-1H-imidazol-1-yl)meth­yl]-1,3,4-thia­diazol-2-amine
title_short 5-[(2-Methyl-4-nitro-1H-imidazol-1-yl)meth­yl]-1,3,4-thia­diazol-2-amine
title_sort 5-[(2-methyl-4-nitro-1h-imidazol-1-yl)meth­yl]-1,3,4-thia­diazol-2-amine
topic Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3885074/
https://www.ncbi.nlm.nih.gov/pubmed/24454250
http://dx.doi.org/10.1107/S1600536813030821
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