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5-[(tert-Butyldiphenylsilyloxy)methyl]pyridazin-3(2H)-one
In the title compound, C(21)H(24)N(2)O(2)Si, a new pyridazin-3(2H)-one derivative, the carbonyl group of the heterocyclic ring and the O atom of the silyl ether are located on the same side of the pyridazinone ring and the C—C—O—Si torsion angle is −140.69 (17)°. In the crystal, molecules are linke...
Autores principales: | , , , |
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Formato: | Online Artículo Texto |
Lenguaje: | English |
Publicado: |
International Union of Crystallography
2013
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3885075/ https://www.ncbi.nlm.nih.gov/pubmed/24454251 http://dx.doi.org/10.1107/S160053681303167X |
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author | Costas-Lago, María Carmen Costas, Tamara Vila, Noemí Terán, Carmen |
author_facet | Costas-Lago, María Carmen Costas, Tamara Vila, Noemí Terán, Carmen |
author_sort | Costas-Lago, María Carmen |
collection | PubMed |
description | In the title compound, C(21)H(24)N(2)O(2)Si, a new pyridazin-3(2H)-one derivative, the carbonyl group of the heterocyclic ring and the O atom of the silyl ether are located on the same side of the pyridazinone ring and the C—C—O—Si torsion angle is −140.69 (17)°. In the crystal, molecules are linked by pairs of strong N—H⋯O hydrogen bonds into centrosymmetric dimers with graph-set notation R (2) (2)(8). Weak C—H⋯π interactions are also observed. |
format | Online Article Text |
id | pubmed-3885075 |
institution | National Center for Biotechnology Information |
language | English |
publishDate | 2013 |
publisher | International Union of Crystallography |
record_format | MEDLINE/PubMed |
spelling | pubmed-38850752014-01-17 5-[(tert-Butyldiphenylsilyloxy)methyl]pyridazin-3(2H)-one Costas-Lago, María Carmen Costas, Tamara Vila, Noemí Terán, Carmen Acta Crystallogr Sect E Struct Rep Online Organic Papers In the title compound, C(21)H(24)N(2)O(2)Si, a new pyridazin-3(2H)-one derivative, the carbonyl group of the heterocyclic ring and the O atom of the silyl ether are located on the same side of the pyridazinone ring and the C—C—O—Si torsion angle is −140.69 (17)°. In the crystal, molecules are linked by pairs of strong N—H⋯O hydrogen bonds into centrosymmetric dimers with graph-set notation R (2) (2)(8). Weak C—H⋯π interactions are also observed. International Union of Crystallography 2013-11-27 /pmc/articles/PMC3885075/ /pubmed/24454251 http://dx.doi.org/10.1107/S160053681303167X Text en © Costas-Lago et al. 2013 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited. |
spellingShingle | Organic Papers Costas-Lago, María Carmen Costas, Tamara Vila, Noemí Terán, Carmen 5-[(tert-Butyldiphenylsilyloxy)methyl]pyridazin-3(2H)-one |
title | 5-[(tert-Butyldiphenylsilyloxy)methyl]pyridazin-3(2H)-one |
title_full | 5-[(tert-Butyldiphenylsilyloxy)methyl]pyridazin-3(2H)-one |
title_fullStr | 5-[(tert-Butyldiphenylsilyloxy)methyl]pyridazin-3(2H)-one |
title_full_unstemmed | 5-[(tert-Butyldiphenylsilyloxy)methyl]pyridazin-3(2H)-one |
title_short | 5-[(tert-Butyldiphenylsilyloxy)methyl]pyridazin-3(2H)-one |
title_sort | 5-[(tert-butyldiphenylsilyloxy)methyl]pyridazin-3(2h)-one |
topic | Organic Papers |
url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3885075/ https://www.ncbi.nlm.nih.gov/pubmed/24454251 http://dx.doi.org/10.1107/S160053681303167X |
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