N′-[(E)-2-Fluoro­benzyl­idene]benzo­hydrazide

The asymmetric unit of the title compound, C(14)H(11)FN(2)O, contains two independent mol­ecules, both of which adopt the E conformation with respect to the azomethine C=N bond. The mol­ecules are non-planar, with dihedral angles of 26.92 (12) and 11.36 (11)° between the benzene and phenyl rings. In...

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Detalles Bibliográficos
Autores principales: Sreeja, P. B., Sithambaresan, M., Aiswarya, N., Kurup, M. R. Prathapachandra
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2013
Materias:
Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3885076/
https://www.ncbi.nlm.nih.gov/pubmed/24454252
http://dx.doi.org/10.1107/S1600536813031747
Descripción
Sumario:The asymmetric unit of the title compound, C(14)H(11)FN(2)O, contains two independent mol­ecules, both of which adopt the E conformation with respect to the azomethine C=N bond. The mol­ecules are non-planar, with dihedral angles of 26.92 (12) and 11.36 (11)° between the benzene and phenyl rings. In the crystal, mol­ecules are linked through N—H⋯O=C and N—H⋯N hydrogen bonds into chains along [101]. C—H⋯O contacts link these chains into layers parallel to (001). The three-dimensional crystal packing is stabilized by π–π inter­actions, the shortest separation between the centroids of benzene rings being 3.884 (1) Å.

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