Cargando…

1-(4-Methyl­phenyl­sulfon­yl)-2-{[3-methyl-4-(2,2,2-tri­fluoro­eth­oxy)pyridin-2-yl]methyl­sulfan­yl}-1H-1,3-benzimidazole

In the title compound, C(23)H(20)F(3)N(3)O(3)S(2), the benzo­imidazole unit makes dihedral angles of 5.02 (1) and 76.42 (1)°, respectively, with the pyridine and methyl­benzene rings; the dihedral angle between the pyridine and methyl­benzene rings is 72.19 (1)°. In the crystal, mol­ecules are conne...

Descripción completa

Detalles Bibliográficos
Autores principales: Shivaprasad, C. M., Kumar, S. Madan, Swaroop, T. R., Rangappa, K. S., Lokanath, N. K.
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2013
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3885087/
https://www.ncbi.nlm.nih.gov/pubmed/24454263
http://dx.doi.org/10.1107/S1600536813031899
Descripción
Sumario:In the title compound, C(23)H(20)F(3)N(3)O(3)S(2), the benzo­imidazole unit makes dihedral angles of 5.02 (1) and 76.42 (1)°, respectively, with the pyridine and methyl­benzene rings; the dihedral angle between the pyridine and methyl­benzene rings is 72.19 (1)°. In the crystal, mol­ecules are connected by weak C—H⋯F, C—H⋯O and C—H⋯N hydrogen bonds. Weak C—H⋯π inter­actions and π–π stacking [centroid–centroid distance = 3.6485 (14) Å] are also observed. The overall packing shows a three-dimensional architecture. The crystal structure contains a void of 51 Å(3), but no solvent mol­ecule (hexane or ethyl acetate) is located within it.