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1-(4-Methyl­phenyl­sulfon­yl)-2-{[3-methyl-4-(2,2,2-tri­fluoro­eth­oxy)pyridin-2-yl]methyl­sulfan­yl}-1H-1,3-benzimidazole

In the title compound, C(23)H(20)F(3)N(3)O(3)S(2), the benzo­imidazole unit makes dihedral angles of 5.02 (1) and 76.42 (1)°, respectively, with the pyridine and methyl­benzene rings; the dihedral angle between the pyridine and methyl­benzene rings is 72.19 (1)°. In the crystal, mol­ecules are conne...

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Autores principales: Shivaprasad, C. M., Kumar, S. Madan, Swaroop, T. R., Rangappa, K. S., Lokanath, N. K.
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2013
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3885087/
https://www.ncbi.nlm.nih.gov/pubmed/24454263
http://dx.doi.org/10.1107/S1600536813031899
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author Shivaprasad, C. M.
Kumar, S. Madan
Swaroop, T. R.
Rangappa, K. S.
Lokanath, N. K.
author_facet Shivaprasad, C. M.
Kumar, S. Madan
Swaroop, T. R.
Rangappa, K. S.
Lokanath, N. K.
author_sort Shivaprasad, C. M.
collection PubMed
description In the title compound, C(23)H(20)F(3)N(3)O(3)S(2), the benzo­imidazole unit makes dihedral angles of 5.02 (1) and 76.42 (1)°, respectively, with the pyridine and methyl­benzene rings; the dihedral angle between the pyridine and methyl­benzene rings is 72.19 (1)°. In the crystal, mol­ecules are connected by weak C—H⋯F, C—H⋯O and C—H⋯N hydrogen bonds. Weak C—H⋯π inter­actions and π–π stacking [centroid–centroid distance = 3.6485 (14) Å] are also observed. The overall packing shows a three-dimensional architecture. The crystal structure contains a void of 51 Å(3), but no solvent mol­ecule (hexane or ethyl acetate) is located within it.
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spelling pubmed-38850872014-01-17 1-(4-Methyl­phenyl­sulfon­yl)-2-{[3-methyl-4-(2,2,2-tri­fluoro­eth­oxy)pyridin-2-yl]methyl­sulfan­yl}-1H-1,3-benzimidazole Shivaprasad, C. M. Kumar, S. Madan Swaroop, T. R. Rangappa, K. S. Lokanath, N. K. Acta Crystallogr Sect E Struct Rep Online Organic Papers In the title compound, C(23)H(20)F(3)N(3)O(3)S(2), the benzo­imidazole unit makes dihedral angles of 5.02 (1) and 76.42 (1)°, respectively, with the pyridine and methyl­benzene rings; the dihedral angle between the pyridine and methyl­benzene rings is 72.19 (1)°. In the crystal, mol­ecules are connected by weak C—H⋯F, C—H⋯O and C—H⋯N hydrogen bonds. Weak C—H⋯π inter­actions and π–π stacking [centroid–centroid distance = 3.6485 (14) Å] are also observed. The overall packing shows a three-dimensional architecture. The crystal structure contains a void of 51 Å(3), but no solvent mol­ecule (hexane or ethyl acetate) is located within it. International Union of Crystallography 2013-11-30 /pmc/articles/PMC3885087/ /pubmed/24454263 http://dx.doi.org/10.1107/S1600536813031899 Text en © Shivaprasad et al. 2013 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Organic Papers
Shivaprasad, C. M.
Kumar, S. Madan
Swaroop, T. R.
Rangappa, K. S.
Lokanath, N. K.
1-(4-Methyl­phenyl­sulfon­yl)-2-{[3-methyl-4-(2,2,2-tri­fluoro­eth­oxy)pyridin-2-yl]methyl­sulfan­yl}-1H-1,3-benzimidazole
title 1-(4-Methyl­phenyl­sulfon­yl)-2-{[3-methyl-4-(2,2,2-tri­fluoro­eth­oxy)pyridin-2-yl]methyl­sulfan­yl}-1H-1,3-benzimidazole
title_full 1-(4-Methyl­phenyl­sulfon­yl)-2-{[3-methyl-4-(2,2,2-tri­fluoro­eth­oxy)pyridin-2-yl]methyl­sulfan­yl}-1H-1,3-benzimidazole
title_fullStr 1-(4-Methyl­phenyl­sulfon­yl)-2-{[3-methyl-4-(2,2,2-tri­fluoro­eth­oxy)pyridin-2-yl]methyl­sulfan­yl}-1H-1,3-benzimidazole
title_full_unstemmed 1-(4-Methyl­phenyl­sulfon­yl)-2-{[3-methyl-4-(2,2,2-tri­fluoro­eth­oxy)pyridin-2-yl]methyl­sulfan­yl}-1H-1,3-benzimidazole
title_short 1-(4-Methyl­phenyl­sulfon­yl)-2-{[3-methyl-4-(2,2,2-tri­fluoro­eth­oxy)pyridin-2-yl]methyl­sulfan­yl}-1H-1,3-benzimidazole
title_sort 1-(4-methyl­phenyl­sulfon­yl)-2-{[3-methyl-4-(2,2,2-tri­fluoro­eth­oxy)pyridin-2-yl]methyl­sulfan­yl}-1h-1,3-benzimidazole
topic Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3885087/
https://www.ncbi.nlm.nih.gov/pubmed/24454263
http://dx.doi.org/10.1107/S1600536813031899
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