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N-(1-Allyl-1H-indazol-5-yl)-4-methyl­benzene­sulfonamide

The asymmetric unit of the title compound, C(17)H(17)N(3)O(2)S, contains two independent mol­ecules linked by an N—H⋯O hydrogen bond. The mol­ecules show different conformations. In the first mol­ecule, the fused five- and six-membered ring system is almost perpendicular to the plane through the ato...

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Autores principales: Chicha, Hakima, Rakib, El Mostapha, Abderrafia, Hafid, Saadi, Mohamed, El Ammari, Lahcen
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2013
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3885088/
https://www.ncbi.nlm.nih.gov/pubmed/24454264
http://dx.doi.org/10.1107/S1600536813032091
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author Chicha, Hakima
Rakib, El Mostapha
Abderrafia, Hafid
Saadi, Mohamed
El Ammari, Lahcen
author_facet Chicha, Hakima
Rakib, El Mostapha
Abderrafia, Hafid
Saadi, Mohamed
El Ammari, Lahcen
author_sort Chicha, Hakima
collection PubMed
description The asymmetric unit of the title compound, C(17)H(17)N(3)O(2)S, contains two independent mol­ecules linked by an N—H⋯O hydrogen bond. The mol­ecules show different conformations. In the first mol­ecule, the fused five- and six-membered ring system is almost perpendicular to the plane through the atoms forming the allyl group, as indicated by the dihedral angle of 85.1 (4)°. The dihedral angle with the methyl­benzene­sulfonamide group is 78.8 (1)°. On the other hand, in the second mol­ecule, the dihedral angles between the indazole plane and the allyl and methyl­benzene­sulfonamide groups are 80.3 (3) and 41.5 (1)°, respectively. In the crystal, mol­ecules are further linked by N—H⋯N and C—H⋯O hydrogen bonds, forming a three-dimensional network.
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spelling pubmed-38850882014-01-17 N-(1-Allyl-1H-indazol-5-yl)-4-methyl­benzene­sulfonamide Chicha, Hakima Rakib, El Mostapha Abderrafia, Hafid Saadi, Mohamed El Ammari, Lahcen Acta Crystallogr Sect E Struct Rep Online Organic Papers The asymmetric unit of the title compound, C(17)H(17)N(3)O(2)S, contains two independent mol­ecules linked by an N—H⋯O hydrogen bond. The mol­ecules show different conformations. In the first mol­ecule, the fused five- and six-membered ring system is almost perpendicular to the plane through the atoms forming the allyl group, as indicated by the dihedral angle of 85.1 (4)°. The dihedral angle with the methyl­benzene­sulfonamide group is 78.8 (1)°. On the other hand, in the second mol­ecule, the dihedral angles between the indazole plane and the allyl and methyl­benzene­sulfonamide groups are 80.3 (3) and 41.5 (1)°, respectively. In the crystal, mol­ecules are further linked by N—H⋯N and C—H⋯O hydrogen bonds, forming a three-dimensional network. International Union of Crystallography 2013-11-30 /pmc/articles/PMC3885088/ /pubmed/24454264 http://dx.doi.org/10.1107/S1600536813032091 Text en © Chicha et al. 2013 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Organic Papers
Chicha, Hakima
Rakib, El Mostapha
Abderrafia, Hafid
Saadi, Mohamed
El Ammari, Lahcen
N-(1-Allyl-1H-indazol-5-yl)-4-methyl­benzene­sulfonamide
title N-(1-Allyl-1H-indazol-5-yl)-4-methyl­benzene­sulfonamide
title_full N-(1-Allyl-1H-indazol-5-yl)-4-methyl­benzene­sulfonamide
title_fullStr N-(1-Allyl-1H-indazol-5-yl)-4-methyl­benzene­sulfonamide
title_full_unstemmed N-(1-Allyl-1H-indazol-5-yl)-4-methyl­benzene­sulfonamide
title_short N-(1-Allyl-1H-indazol-5-yl)-4-methyl­benzene­sulfonamide
title_sort n-(1-allyl-1h-indazol-5-yl)-4-methyl­benzene­sulfonamide
topic Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3885088/
https://www.ncbi.nlm.nih.gov/pubmed/24454264
http://dx.doi.org/10.1107/S1600536813032091
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