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(3aR,8bR)-3a,8b-Dihydroxy-1-(4-methoxyphenyl)-2-methylsulfanyl-3-nitro-1,8b-dihydroindeno[1,2-b]pyrrol-4(3aH)-one
In the title compound, C(19)H(16)N(2)O(6)S, the pyrrolidine ring adopts a twisted conformation with puckering parameters q (2) = 0.088 (3) Å and Φ(2) = 61.5 (14)°. The cyclopentane ring adopts a twisted conformation with puckering parameters q (2) = 0.099 (2) Å and Φ(2) = 242.8 (14)°. A weak intra...
Autores principales: | , , , , |
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Formato: | Online Artículo Texto |
Lenguaje: | English |
Publicado: |
International Union of Crystallography
2013
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3885090/ https://www.ncbi.nlm.nih.gov/pubmed/24454266 http://dx.doi.org/10.1107/S1600536813031279 |
Sumario: | In the title compound, C(19)H(16)N(2)O(6)S, the pyrrolidine ring adopts a twisted conformation with puckering parameters q (2) = 0.088 (3) Å and Φ(2) = 61.5 (14)°. The cyclopentane ring adopts a twisted conformation with puckering parameters q (2) = 0.099 (2) Å and Φ(2) = 242.8 (14)°. A weak intramolecular O—H⋯O interaction occurs. In the crystal, pairs of C—H⋯O interactions generate dimers with graph-set motif R (2) (2)(24) and they are interconnected by pairs of O—H⋯O hydrogen bonds, which link the molecules into inversion dimers with graph-set motif R (2) (2)(10). |
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