(S)-4,5-Diphenyl-1-[1-phenyl-3-(phenyl­sulfan­yl)propan-2-yl]-2-(thio­phen-2-yl)-1H-imidazole

In the title compound, C(34)H(28)N(2)S(2), the central imidazole ring (r.m.s. deviation = 0.0015 Å) forms dihedral angles of 55.7 (3), 17.94 (11) and 86.27 (11)°, respectively, with the mean planes of the attached thienyl and two phenyl substituents. The thienyl ring shows ring-flip disorder [occupa...

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Autores principales: Gao, Jie, Wang, Hongyan, Yang, Liangru, Xiao, Yongmei, Mao, Pu
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2013
Materias:
Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3885095/
https://www.ncbi.nlm.nih.gov/pubmed/24454271
http://dx.doi.org/10.1107/S1600536813032066
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author Gao, Jie
Wang, Hongyan
Yang, Liangru
Xiao, Yongmei
Mao, Pu
author_facet Gao, Jie
Wang, Hongyan
Yang, Liangru
Xiao, Yongmei
Mao, Pu
author_sort Gao, Jie
collection PubMed
description In the title compound, C(34)H(28)N(2)S(2), the central imidazole ring (r.m.s. deviation = 0.0015 Å) forms dihedral angles of 55.7 (3), 17.94 (11) and 86.27 (11)°, respectively, with the mean planes of the attached thienyl and two phenyl substituents. The thienyl ring shows ring-flip disorder [occupancy ratio = 0.647 (2):0.353 (2)]. The chiral centre maintains the S configuration of the l-phenyl­alaninol starting material. Intra- and inter­molecular C—H⋯S hydrogen bonds involving the disordered thienyl ring are observed.
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spelling pubmed-38850952014-01-17 (S)-4,5-Diphenyl-1-[1-phenyl-3-(phenyl­sulfan­yl)propan-2-yl]-2-(thio­phen-2-yl)-1H-imidazole Gao, Jie Wang, Hongyan Yang, Liangru Xiao, Yongmei Mao, Pu Acta Crystallogr Sect E Struct Rep Online Organic Papers In the title compound, C(34)H(28)N(2)S(2), the central imidazole ring (r.m.s. deviation = 0.0015 Å) forms dihedral angles of 55.7 (3), 17.94 (11) and 86.27 (11)°, respectively, with the mean planes of the attached thienyl and two phenyl substituents. The thienyl ring shows ring-flip disorder [occupancy ratio = 0.647 (2):0.353 (2)]. The chiral centre maintains the S configuration of the l-phenyl­alaninol starting material. Intra- and inter­molecular C—H⋯S hydrogen bonds involving the disordered thienyl ring are observed. International Union of Crystallography 2013-11-30 /pmc/articles/PMC3885095/ /pubmed/24454271 http://dx.doi.org/10.1107/S1600536813032066 Text en © Gao et al. 2013 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Organic Papers
Gao, Jie
Wang, Hongyan
Yang, Liangru
Xiao, Yongmei
Mao, Pu
(S)-4,5-Diphenyl-1-[1-phenyl-3-(phenyl­sulfan­yl)propan-2-yl]-2-(thio­phen-2-yl)-1H-imidazole
title (S)-4,5-Diphenyl-1-[1-phenyl-3-(phenyl­sulfan­yl)propan-2-yl]-2-(thio­phen-2-yl)-1H-imidazole
title_full (S)-4,5-Diphenyl-1-[1-phenyl-3-(phenyl­sulfan­yl)propan-2-yl]-2-(thio­phen-2-yl)-1H-imidazole
title_fullStr (S)-4,5-Diphenyl-1-[1-phenyl-3-(phenyl­sulfan­yl)propan-2-yl]-2-(thio­phen-2-yl)-1H-imidazole
title_full_unstemmed (S)-4,5-Diphenyl-1-[1-phenyl-3-(phenyl­sulfan­yl)propan-2-yl]-2-(thio­phen-2-yl)-1H-imidazole
title_short (S)-4,5-Diphenyl-1-[1-phenyl-3-(phenyl­sulfan­yl)propan-2-yl]-2-(thio­phen-2-yl)-1H-imidazole
title_sort (s)-4,5-diphenyl-1-[1-phenyl-3-(phenyl­sulfan­yl)propan-2-yl]-2-(thio­phen-2-yl)-1h-imidazole
topic Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3885095/
https://www.ncbi.nlm.nih.gov/pubmed/24454271
http://dx.doi.org/10.1107/S1600536813032066
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