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Thermodynamic and Differential Entropy under a Change of Variables
The differential Shannon entropy of information theory can change under a change of variables (coordinates), but the thermodynamic entropy of a physical system must be invariant under such a change. This difference is puzzling, because the Shannon and Gibbs entropies have the same functional form. W...
Autores principales: | , |
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Formato: | Online Artículo Texto |
Lenguaje: | English |
Publicado: |
2010
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3891802/ https://www.ncbi.nlm.nih.gov/pubmed/24436633 http://dx.doi.org/10.3390/e12030578 |
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author | Hnizdo, Vladimir Gilson, Michael K. |
author_facet | Hnizdo, Vladimir Gilson, Michael K. |
author_sort | Hnizdo, Vladimir |
collection | PubMed |
description | The differential Shannon entropy of information theory can change under a change of variables (coordinates), but the thermodynamic entropy of a physical system must be invariant under such a change. This difference is puzzling, because the Shannon and Gibbs entropies have the same functional form. We show that a canonical change of variables can, indeed, alter the spatial component of the thermodynamic entropy just as it alters the differential Shannon entropy. However, there is also a momentum part of the entropy, which turns out to undergo an equal and opposite change when the coordinates are transformed, so that the total thermodynamic entropy remains invariant. We furthermore show how one may correctly write the change in total entropy for an isothermal physical process in any set of spatial coordinates. |
format | Online Article Text |
id | pubmed-3891802 |
institution | National Center for Biotechnology Information |
language | English |
publishDate | 2010 |
record_format | MEDLINE/PubMed |
spelling | pubmed-38918022014-01-14 Thermodynamic and Differential Entropy under a Change of Variables Hnizdo, Vladimir Gilson, Michael K. Entropy (Basel) Article The differential Shannon entropy of information theory can change under a change of variables (coordinates), but the thermodynamic entropy of a physical system must be invariant under such a change. This difference is puzzling, because the Shannon and Gibbs entropies have the same functional form. We show that a canonical change of variables can, indeed, alter the spatial component of the thermodynamic entropy just as it alters the differential Shannon entropy. However, there is also a momentum part of the entropy, which turns out to undergo an equal and opposite change when the coordinates are transformed, so that the total thermodynamic entropy remains invariant. We furthermore show how one may correctly write the change in total entropy for an isothermal physical process in any set of spatial coordinates. 2010-03-16 /pmc/articles/PMC3891802/ /pubmed/24436633 http://dx.doi.org/10.3390/e12030578 Text en © 2010 by the authors licensee Molecular Diversity Preservation International, Basel, Switzerland This article is an open-access article distributed under the terms and conditions of the Creative Commons Attribution license http://creativecommons.org/licenses/by/3.0/. |
spellingShingle | Article Hnizdo, Vladimir Gilson, Michael K. Thermodynamic and Differential Entropy under a Change of Variables |
title | Thermodynamic and Differential Entropy under a Change of Variables |
title_full | Thermodynamic and Differential Entropy under a Change of Variables |
title_fullStr | Thermodynamic and Differential Entropy under a Change of Variables |
title_full_unstemmed | Thermodynamic and Differential Entropy under a Change of Variables |
title_short | Thermodynamic and Differential Entropy under a Change of Variables |
title_sort | thermodynamic and differential entropy under a change of variables |
topic | Article |
url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3891802/ https://www.ncbi.nlm.nih.gov/pubmed/24436633 http://dx.doi.org/10.3390/e12030578 |
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