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Thermodynamic and Differential Entropy under a Change of Variables

The differential Shannon entropy of information theory can change under a change of variables (coordinates), but the thermodynamic entropy of a physical system must be invariant under such a change. This difference is puzzling, because the Shannon and Gibbs entropies have the same functional form. W...

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Detalles Bibliográficos
Autores principales: Hnizdo, Vladimir, Gilson, Michael K.
Formato: Online Artículo Texto
Lenguaje:English
Publicado: 2010
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3891802/
https://www.ncbi.nlm.nih.gov/pubmed/24436633
http://dx.doi.org/10.3390/e12030578
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author Hnizdo, Vladimir
Gilson, Michael K.
author_facet Hnizdo, Vladimir
Gilson, Michael K.
author_sort Hnizdo, Vladimir
collection PubMed
description The differential Shannon entropy of information theory can change under a change of variables (coordinates), but the thermodynamic entropy of a physical system must be invariant under such a change. This difference is puzzling, because the Shannon and Gibbs entropies have the same functional form. We show that a canonical change of variables can, indeed, alter the spatial component of the thermodynamic entropy just as it alters the differential Shannon entropy. However, there is also a momentum part of the entropy, which turns out to undergo an equal and opposite change when the coordinates are transformed, so that the total thermodynamic entropy remains invariant. We furthermore show how one may correctly write the change in total entropy for an isothermal physical process in any set of spatial coordinates.
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spelling pubmed-38918022014-01-14 Thermodynamic and Differential Entropy under a Change of Variables Hnizdo, Vladimir Gilson, Michael K. Entropy (Basel) Article The differential Shannon entropy of information theory can change under a change of variables (coordinates), but the thermodynamic entropy of a physical system must be invariant under such a change. This difference is puzzling, because the Shannon and Gibbs entropies have the same functional form. We show that a canonical change of variables can, indeed, alter the spatial component of the thermodynamic entropy just as it alters the differential Shannon entropy. However, there is also a momentum part of the entropy, which turns out to undergo an equal and opposite change when the coordinates are transformed, so that the total thermodynamic entropy remains invariant. We furthermore show how one may correctly write the change in total entropy for an isothermal physical process in any set of spatial coordinates. 2010-03-16 /pmc/articles/PMC3891802/ /pubmed/24436633 http://dx.doi.org/10.3390/e12030578 Text en © 2010 by the authors licensee Molecular Diversity Preservation International, Basel, Switzerland This article is an open-access article distributed under the terms and conditions of the Creative Commons Attribution license http://creativecommons.org/licenses/by/3.0/.
spellingShingle Article
Hnizdo, Vladimir
Gilson, Michael K.
Thermodynamic and Differential Entropy under a Change of Variables
title Thermodynamic and Differential Entropy under a Change of Variables
title_full Thermodynamic and Differential Entropy under a Change of Variables
title_fullStr Thermodynamic and Differential Entropy under a Change of Variables
title_full_unstemmed Thermodynamic and Differential Entropy under a Change of Variables
title_short Thermodynamic and Differential Entropy under a Change of Variables
title_sort thermodynamic and differential entropy under a change of variables
topic Article
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3891802/
https://www.ncbi.nlm.nih.gov/pubmed/24436633
http://dx.doi.org/10.3390/e12030578
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