Equilibrium Study of Pd(dba)(2) and P(OPh)(3) in the Pd-Catalyzed Allylation of Aniline by Allyl Alcohol

[Image: see text] Reaction of Pd(dba)(2) and P(OPh)(3) shows a unique equilibrium where the Pd[P(OPh)(3)](3) complex is favored over both Pd(dba)[P(OPh)(3)](2) and Pd[P(OPh)(3)](4) complexes at room temperature. At a lower temperature, Pd[P(OPh)(3)](4) becomes the most abundant complex in solution....

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Detalles Bibliográficos
Autores principales: Sawadjoon, Supaporn, Orthaber, Andreas, Sjöberg, Per J. R., Eriksson, Lars, Samec, Joseph S. M.
Formato: Online Artículo Texto
Lenguaje:English
Publicado: American Chemical Society 2013
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3893935/
https://www.ncbi.nlm.nih.gov/pubmed/24465076
http://dx.doi.org/10.1021/om4009873

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