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Photoinduced Brook-Type Rearrangement of Acylcyclopolysilanes
[Image: see text] Previously unknown 1,1,4-tris(trimethylsilyl)-4-acyldodecamethylcyclohexasilanes (Me(3)Si)(2)Si(6)Me(12)(Me(3)Si)COR (16a, R = tert-butyl; 16b, R = 1-adamantyl) have been synthesized by the reaction of the potassium silanides (Me(3)Si)(2)Si(6)Me(12)(Me(3)Si)K with acid chlorides Cl...
| Autores principales: | , , , , , |
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| Formato: | Online Artículo Texto |
| Lenguaje: | English |
| Publicado: |
American Chemical
Society
2013
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| Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3893937/ https://www.ncbi.nlm.nih.gov/pubmed/24465075 http://dx.doi.org/10.1021/om4009845 |