Ethyl 4-(4-chloro­anilino)-1-(4-chloro­phen­yl)-2-methyl-5-oxo-2,5-di­hydro-1H-pyrrole-2-carboxyl­ate

In the title compound, C(20)H(18)Cl(2)N(2)O(3), the dihedral angles between the central 2,5-di­hydro-1H-pyrrole ring and the phenyl rings are 74.87 (9) and 29.09 (9)°. Intra­molecular N—H⋯O and C—H⋯O hydrogen bonds occur. In the crystal, pairs of N—H⋯O hydrogen bonds link adjacent mol­ecules into in...

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Autores principales: Akkurt, Mehmet, Mohamed, Shaaban K., Elremaily, Mahmoud A.A., Santoyo-Gonzalez, Francisco, Albayati, Mustafa R.
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2013
Materias:
Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3894618/
https://www.ncbi.nlm.nih.gov/pubmed/24454212
http://dx.doi.org/10.1107/S1600536813030560
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author Akkurt, Mehmet
Mohamed, Shaaban K.
Elremaily, Mahmoud A.A.
Santoyo-Gonzalez, Francisco
Albayati, Mustafa R.
author_facet Akkurt, Mehmet
Mohamed, Shaaban K.
Elremaily, Mahmoud A.A.
Santoyo-Gonzalez, Francisco
Albayati, Mustafa R.
author_sort Akkurt, Mehmet
collection PubMed
description In the title compound, C(20)H(18)Cl(2)N(2)O(3), the dihedral angles between the central 2,5-di­hydro-1H-pyrrole ring and the phenyl rings are 74.87 (9) and 29.09 (9)°. Intra­molecular N—H⋯O and C—H⋯O hydrogen bonds occur. In the crystal, pairs of N—H⋯O hydrogen bonds link adjacent mol­ecules into inversion dimers and form an R (1) (2)(6)R (2) (2)(10)R (1) (2)(6) ring motif through C—H⋯O hydrogen bonds.
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spelling pubmed-38946182014-01-17 Ethyl 4-(4-chloro­anilino)-1-(4-chloro­phen­yl)-2-methyl-5-oxo-2,5-di­hydro-1H-pyrrole-2-carboxyl­ate Akkurt, Mehmet Mohamed, Shaaban K. Elremaily, Mahmoud A.A. Santoyo-Gonzalez, Francisco Albayati, Mustafa R. Acta Crystallogr Sect E Struct Rep Online Organic Papers In the title compound, C(20)H(18)Cl(2)N(2)O(3), the dihedral angles between the central 2,5-di­hydro-1H-pyrrole ring and the phenyl rings are 74.87 (9) and 29.09 (9)°. Intra­molecular N—H⋯O and C—H⋯O hydrogen bonds occur. In the crystal, pairs of N—H⋯O hydrogen bonds link adjacent mol­ecules into inversion dimers and form an R (1) (2)(6)R (2) (2)(10)R (1) (2)(6) ring motif through C—H⋯O hydrogen bonds. International Union of Crystallography 2013-12-03 /pmc/articles/PMC3894618/ /pubmed/24454212 http://dx.doi.org/10.1107/S1600536813030560 Text en © Akkurt et al. 2013 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Organic Papers
Akkurt, Mehmet
Mohamed, Shaaban K.
Elremaily, Mahmoud A.A.
Santoyo-Gonzalez, Francisco
Albayati, Mustafa R.
Ethyl 4-(4-chloro­anilino)-1-(4-chloro­phen­yl)-2-methyl-5-oxo-2,5-di­hydro-1H-pyrrole-2-carboxyl­ate
title Ethyl 4-(4-chloro­anilino)-1-(4-chloro­phen­yl)-2-methyl-5-oxo-2,5-di­hydro-1H-pyrrole-2-carboxyl­ate
title_full Ethyl 4-(4-chloro­anilino)-1-(4-chloro­phen­yl)-2-methyl-5-oxo-2,5-di­hydro-1H-pyrrole-2-carboxyl­ate
title_fullStr Ethyl 4-(4-chloro­anilino)-1-(4-chloro­phen­yl)-2-methyl-5-oxo-2,5-di­hydro-1H-pyrrole-2-carboxyl­ate
title_full_unstemmed Ethyl 4-(4-chloro­anilino)-1-(4-chloro­phen­yl)-2-methyl-5-oxo-2,5-di­hydro-1H-pyrrole-2-carboxyl­ate
title_short Ethyl 4-(4-chloro­anilino)-1-(4-chloro­phen­yl)-2-methyl-5-oxo-2,5-di­hydro-1H-pyrrole-2-carboxyl­ate
title_sort ethyl 4-(4-chloro­anilino)-1-(4-chloro­phen­yl)-2-methyl-5-oxo-2,5-di­hydro-1h-pyrrole-2-carboxyl­ate
topic Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3894618/
https://www.ncbi.nlm.nih.gov/pubmed/24454212
http://dx.doi.org/10.1107/S1600536813030560
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