Mechanistic and Chiroptical Studies on the Desulfurization of Epidithiodioxopiperazines Reveal Universal Retention of Configuration at the Bridgehead Carbon Atoms

[Image: see text] The stereochemistry of the desulfurization products of chiral natural and synthetic 3,6-epidithiodiketopiperazines (ETPs) is specified inconsistently in the literature. Qualitative mechanisms have been put forward to explain apparently divergent stereochemical pathways, but the qua...

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Detalles Bibliográficos
Autores principales: Cherblanc, Fanny L., Lo, Ya-Pei, Herrebout, Wouter A., Bultinck, Patrick, Rzepa, Henry S., Fuchter, Matthew J.
Formato: Online Artículo Texto
Lenguaje:English
Publicado: American Chemical Society 2013
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3894640/
https://www.ncbi.nlm.nih.gov/pubmed/24073665
http://dx.doi.org/10.1021/jo401316a

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