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The difluoromethylene (CF(2)) group in aliphatic chains: Synthesis and conformational preference of palmitic acids and nonadecane containing CF(2) groups

The syntheses of palmitic acids and a nonadecane are reported with CF(2) groups located 1,3 or 1,4 to each other along the aliphatic chain. Specifically 8,8,10,10- and 8,8,11,11-tetrafluorohexadecanoic acids (6b and 6c) are prepared as well as the singly modified analogue 8,8-difluorohexadecanoic ac...

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Detalles Bibliográficos
Autores principales: Wang, Yi, Callejo, Ricardo, Slawin, Alexandra M Z, O’Hagan, David
Formato: Online Artículo Texto
Lenguaje:English
Publicado: Beilstein-Institut 2014
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3896246/
https://www.ncbi.nlm.nih.gov/pubmed/24454560
http://dx.doi.org/10.3762/bjoc.10.4

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