Nickel(II) uranium(IV) tris­ulfide

Crystals of NiUS(3) were obtained from the reaction of the elements Ni, U, S, and of GeI(2) in a CsCl flux at 1173 K. Nickel(II) uranium(IV) tris­ulfide, NiUS(3), has ortho­rhom­bic (Pnma) symmetry and crystallizes in the GdFeO(3) structure type. The compound has a perovskite ABQ (3)-like structure,...

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Detalles Bibliográficos
Autores principales: Ward, Matthew D., Ibers, James A.
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2013
Materias:
Inorganic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3914034/
https://www.ncbi.nlm.nih.gov/pubmed/24526939
http://dx.doi.org/10.1107/S1600536813033680
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author Ward, Matthew D.
Ibers, James A.
author_facet Ward, Matthew D.
Ibers, James A.
author_sort Ward, Matthew D.
collection PubMed
description Crystals of NiUS(3) were obtained from the reaction of the elements Ni, U, S, and of GeI(2) in a CsCl flux at 1173 K. Nickel(II) uranium(IV) tris­ulfide, NiUS(3), has ortho­rhom­bic (Pnma) symmetry and crystallizes in the GdFeO(3) structure type. The compound has a perovskite ABQ (3)-like structure, with U occupying the inter­stitial sites of a NiS(6) framework. The U atoms are coordinated by eight S atoms in a distorted bicapped trigonal–prismatic arrangement. The Ni atoms are coordinated by six S atoms in a slightly distorted octa­hedral arrangement. The asymmetric unit comprises one U site (site symmetry .m.), one Ni site (-1), and two S sites (1 and .m.).
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spelling pubmed-39140342014-02-13 Nickel(II) uranium(IV) tris­ulfide Ward, Matthew D. Ibers, James A. Acta Crystallogr Sect E Struct Rep Online Inorganic Papers Crystals of NiUS(3) were obtained from the reaction of the elements Ni, U, S, and of GeI(2) in a CsCl flux at 1173 K. Nickel(II) uranium(IV) tris­ulfide, NiUS(3), has ortho­rhom­bic (Pnma) symmetry and crystallizes in the GdFeO(3) structure type. The compound has a perovskite ABQ (3)-like structure, with U occupying the inter­stitial sites of a NiS(6) framework. The U atoms are coordinated by eight S atoms in a distorted bicapped trigonal–prismatic arrangement. The Ni atoms are coordinated by six S atoms in a slightly distorted octa­hedral arrangement. The asymmetric unit comprises one U site (site symmetry .m.), one Ni site (-1), and two S sites (1 and .m.). International Union of Crystallography 2013-12-21 /pmc/articles/PMC3914034/ /pubmed/24526939 http://dx.doi.org/10.1107/S1600536813033680 Text en © Ward and Ibers 2014 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Inorganic Papers
Ward, Matthew D.
Ibers, James A.
Nickel(II) uranium(IV) tris­ulfide
title Nickel(II) uranium(IV) tris­ulfide
title_full Nickel(II) uranium(IV) tris­ulfide
title_fullStr Nickel(II) uranium(IV) tris­ulfide
title_full_unstemmed Nickel(II) uranium(IV) tris­ulfide
title_short Nickel(II) uranium(IV) tris­ulfide
title_sort nickel(ii) uranium(iv) tris­ulfide
topic Inorganic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3914034/
https://www.ncbi.nlm.nih.gov/pubmed/24526939
http://dx.doi.org/10.1107/S1600536813033680
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