Potassium trinickel(II) orthophosphate diphosphate, KNi(3)(PO(4))P(2)O(7)

The structure of the title compound is characterized by the presence of two different anions, (PO(4))(3−) and (P(2)O(7))(4−) with an eclipsed conformation. The crystal structure consists of edge-sharing [NiO(6)] octa­hedra forming an [Ni(3)O(14)] chain running parallel to [001]. Adjacent chains are...

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Autores principales: Moutataouia, Meryem, Lamire, Mohammed, Saadi, Mohamed, El Ammari, Lahcen
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2013
Materias:
Inorganic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3914035/
https://www.ncbi.nlm.nih.gov/pubmed/24526940
http://dx.doi.org/10.1107/S1600536813034089
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author Moutataouia, Meryem
Lamire, Mohammed
Saadi, Mohamed
El Ammari, Lahcen
author_facet Moutataouia, Meryem
Lamire, Mohammed
Saadi, Mohamed
El Ammari, Lahcen
author_sort Moutataouia, Meryem
collection PubMed
description The structure of the title compound is characterized by the presence of two different anions, (PO(4))(3−) and (P(2)O(7))(4−) with an eclipsed conformation. The crystal structure consists of edge-sharing [NiO(6)] octa­hedra forming an [Ni(3)O(14)] chain running parallel to [001]. Adjacent chains are connected through edges and apices to PO(4) and P(2)O(7) groups in such a way as to build a three-dimensional host lattice. The resulting framework presents inter­secting tunnels running along [010] and [101] in which the 11-coordinated potassium cation is located. The crystal structure of this new phosphate probably represents a new structural type.
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spelling pubmed-39140352014-02-13 Potassium trinickel(II) orthophosphate diphosphate, KNi(3)(PO(4))P(2)O(7) Moutataouia, Meryem Lamire, Mohammed Saadi, Mohamed El Ammari, Lahcen Acta Crystallogr Sect E Struct Rep Online Inorganic Papers The structure of the title compound is characterized by the presence of two different anions, (PO(4))(3−) and (P(2)O(7))(4−) with an eclipsed conformation. The crystal structure consists of edge-sharing [NiO(6)] octa­hedra forming an [Ni(3)O(14)] chain running parallel to [001]. Adjacent chains are connected through edges and apices to PO(4) and P(2)O(7) groups in such a way as to build a three-dimensional host lattice. The resulting framework presents inter­secting tunnels running along [010] and [101] in which the 11-coordinated potassium cation is located. The crystal structure of this new phosphate probably represents a new structural type. International Union of Crystallography 2013-12-24 /pmc/articles/PMC3914035/ /pubmed/24526940 http://dx.doi.org/10.1107/S1600536813034089 Text en © Moutataouia et al. 2014 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Inorganic Papers
Moutataouia, Meryem
Lamire, Mohammed
Saadi, Mohamed
El Ammari, Lahcen
Potassium trinickel(II) orthophosphate diphosphate, KNi(3)(PO(4))P(2)O(7)
title Potassium trinickel(II) orthophosphate diphosphate, KNi(3)(PO(4))P(2)O(7)
title_full Potassium trinickel(II) orthophosphate diphosphate, KNi(3)(PO(4))P(2)O(7)
title_fullStr Potassium trinickel(II) orthophosphate diphosphate, KNi(3)(PO(4))P(2)O(7)
title_full_unstemmed Potassium trinickel(II) orthophosphate diphosphate, KNi(3)(PO(4))P(2)O(7)
title_short Potassium trinickel(II) orthophosphate diphosphate, KNi(3)(PO(4))P(2)O(7)
title_sort potassium trinickel(ii) orthophosphate diphosphate, kni(3)(po(4))p(2)o(7)
topic Inorganic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3914035/
https://www.ncbi.nlm.nih.gov/pubmed/24526940
http://dx.doi.org/10.1107/S1600536813034089
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