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Dichlorido{8-[2-(dimethylamino)ethylamino]quinoline-κ(3) N,N′,N′′}zinc
In the title complex, [ZnCl(2)(C(13)H(17)N(3))], the coordination sphere of the zinc cation is distorted square pyramidal. The three N atoms of the N,N′,N′′-tridentate 8-[2-(dimethylamino)ethylamino]quinoline ligand and one chloride ion constitute a considerably distorted square base. The apica...
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Formato: | Online Artículo Texto |
Lenguaje: | English |
Publicado: |
International Union of Crystallography
2013
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3914037/ https://www.ncbi.nlm.nih.gov/pubmed/24526942 http://dx.doi.org/10.1107/S1600536813029929 |
Sumario: | In the title complex, [ZnCl(2)(C(13)H(17)N(3))], the coordination sphere of the zinc cation is distorted square pyramidal. The three N atoms of the N,N′,N′′-tridentate 8-[2-(dimethylamino)ethylamino]quinoline ligand and one chloride ion constitute a considerably distorted square base. The apical site is occupied by another chloride ion. The distortion from the ideal square-pyramidal geometry is manifested by the N—Zn—N angle of 133.25 (11)°. Like most square-pyramidal metal complexes, the zinc cation is displaced towards the apical chloride ion. In the crystal, molecules are linked by N—H⋯Cl interactions. This leads to the formation of chains of molecules parallel to the b-axis direction. |
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