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Di­chlorido­{8-[2-(di­methyl­amino)­ethyl­amino]­quinoline-κ(3) N,N′,N′′}zinc

In the title complex, [ZnCl(2)(C(13)H(17)N(3))], the coordination sphere of the zinc cation is distorted square pyramidal. The three N atoms of the N,N′,N′′-tridentate 8-[2-(di­methyl­amino)­ethyl­amino]­quinoline ligand and one chloride ion constitute a considerably distorted square base. The apica...

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Detalles Bibliográficos
Autor principal: Al-Sudani, Abdul-Razak H.
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2013
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3914037/
https://www.ncbi.nlm.nih.gov/pubmed/24526942
http://dx.doi.org/10.1107/S1600536813029929
Descripción
Sumario:In the title complex, [ZnCl(2)(C(13)H(17)N(3))], the coordination sphere of the zinc cation is distorted square pyramidal. The three N atoms of the N,N′,N′′-tridentate 8-[2-(di­methyl­amino)­ethyl­amino]­quinoline ligand and one chloride ion constitute a considerably distorted square base. The apical site is occupied by another chloride ion. The distortion from the ideal square-pyramidal geometry is manifested by the N—Zn—N angle of 133.25 (11)°. Like most square-pyramidal metal complexes, the zinc cation is displaced towards the apical chloride ion. In the crystal, mol­ecules are linked by N—H⋯Cl inter­actions. This leads to the formation of chains of mol­ecules parallel to the b-axis direction.