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Dichlorido{8-[2-(dimethylamino)ethylamino]quinoline-κ(3) N,N′,N′′}zinc
In the title complex, [ZnCl(2)(C(13)H(17)N(3))], the coordination sphere of the zinc cation is distorted square pyramidal. The three N atoms of the N,N′,N′′-tridentate 8-[2-(dimethylamino)ethylamino]quinoline ligand and one chloride ion constitute a considerably distorted square base. The apica...
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Formato: | Online Artículo Texto |
Lenguaje: | English |
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International Union of Crystallography
2013
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Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3914037/ https://www.ncbi.nlm.nih.gov/pubmed/24526942 http://dx.doi.org/10.1107/S1600536813029929 |
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author | Al-Sudani, Abdul-Razak H. |
author_facet | Al-Sudani, Abdul-Razak H. |
author_sort | Al-Sudani, Abdul-Razak H. |
collection | PubMed |
description | In the title complex, [ZnCl(2)(C(13)H(17)N(3))], the coordination sphere of the zinc cation is distorted square pyramidal. The three N atoms of the N,N′,N′′-tridentate 8-[2-(dimethylamino)ethylamino]quinoline ligand and one chloride ion constitute a considerably distorted square base. The apical site is occupied by another chloride ion. The distortion from the ideal square-pyramidal geometry is manifested by the N—Zn—N angle of 133.25 (11)°. Like most square-pyramidal metal complexes, the zinc cation is displaced towards the apical chloride ion. In the crystal, molecules are linked by N—H⋯Cl interactions. This leads to the formation of chains of molecules parallel to the b-axis direction. |
format | Online Article Text |
id | pubmed-3914037 |
institution | National Center for Biotechnology Information |
language | English |
publishDate | 2013 |
publisher | International Union of Crystallography |
record_format | MEDLINE/PubMed |
spelling | pubmed-39140372014-02-13 Dichlorido{8-[2-(dimethylamino)ethylamino]quinoline-κ(3) N,N′,N′′}zinc Al-Sudani, Abdul-Razak H. Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers In the title complex, [ZnCl(2)(C(13)H(17)N(3))], the coordination sphere of the zinc cation is distorted square pyramidal. The three N atoms of the N,N′,N′′-tridentate 8-[2-(dimethylamino)ethylamino]quinoline ligand and one chloride ion constitute a considerably distorted square base. The apical site is occupied by another chloride ion. The distortion from the ideal square-pyramidal geometry is manifested by the N—Zn—N angle of 133.25 (11)°. Like most square-pyramidal metal complexes, the zinc cation is displaced towards the apical chloride ion. In the crystal, molecules are linked by N—H⋯Cl interactions. This leads to the formation of chains of molecules parallel to the b-axis direction. International Union of Crystallography 2013-12-04 /pmc/articles/PMC3914037/ /pubmed/24526942 http://dx.doi.org/10.1107/S1600536813029929 Text en © Abdul-Razak H. Al-Sudani 2014 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited. |
spellingShingle | Metal-Organic Papers Al-Sudani, Abdul-Razak H. Dichlorido{8-[2-(dimethylamino)ethylamino]quinoline-κ(3) N,N′,N′′}zinc |
title | Dichlorido{8-[2-(dimethylamino)ethylamino]quinoline-κ(3)
N,N′,N′′}zinc |
title_full | Dichlorido{8-[2-(dimethylamino)ethylamino]quinoline-κ(3)
N,N′,N′′}zinc |
title_fullStr | Dichlorido{8-[2-(dimethylamino)ethylamino]quinoline-κ(3)
N,N′,N′′}zinc |
title_full_unstemmed | Dichlorido{8-[2-(dimethylamino)ethylamino]quinoline-κ(3)
N,N′,N′′}zinc |
title_short | Dichlorido{8-[2-(dimethylamino)ethylamino]quinoline-κ(3)
N,N′,N′′}zinc |
title_sort | dichlorido{8-[2-(dimethylamino)ethylamino]quinoline-κ(3)
n,n′,n′′}zinc |
topic | Metal-Organic Papers |
url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3914037/ https://www.ncbi.nlm.nih.gov/pubmed/24526942 http://dx.doi.org/10.1107/S1600536813029929 |
work_keys_str_mv | AT alsudaniabdulrazakh dichlorido82dimethylaminoethylaminoquinolinek3nnnzinc |