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Di­chlorido­{8-[2-(di­methyl­amino)­ethyl­amino]­quinoline-κ(3) N,N′,N′′}zinc

In the title complex, [ZnCl(2)(C(13)H(17)N(3))], the coordination sphere of the zinc cation is distorted square pyramidal. The three N atoms of the N,N′,N′′-tridentate 8-[2-(di­methyl­amino)­ethyl­amino]­quinoline ligand and one chloride ion constitute a considerably distorted square base. The apica...

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Autor principal: Al-Sudani, Abdul-Razak H.
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2013
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3914037/
https://www.ncbi.nlm.nih.gov/pubmed/24526942
http://dx.doi.org/10.1107/S1600536813029929
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author Al-Sudani, Abdul-Razak H.
author_facet Al-Sudani, Abdul-Razak H.
author_sort Al-Sudani, Abdul-Razak H.
collection PubMed
description In the title complex, [ZnCl(2)(C(13)H(17)N(3))], the coordination sphere of the zinc cation is distorted square pyramidal. The three N atoms of the N,N′,N′′-tridentate 8-[2-(di­methyl­amino)­ethyl­amino]­quinoline ligand and one chloride ion constitute a considerably distorted square base. The apical site is occupied by another chloride ion. The distortion from the ideal square-pyramidal geometry is manifested by the N—Zn—N angle of 133.25 (11)°. Like most square-pyramidal metal complexes, the zinc cation is displaced towards the apical chloride ion. In the crystal, mol­ecules are linked by N—H⋯Cl inter­actions. This leads to the formation of chains of mol­ecules parallel to the b-axis direction.
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spelling pubmed-39140372014-02-13 Di­chlorido­{8-[2-(di­methyl­amino)­ethyl­amino]­quinoline-κ(3) N,N′,N′′}zinc Al-Sudani, Abdul-Razak H. Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers In the title complex, [ZnCl(2)(C(13)H(17)N(3))], the coordination sphere of the zinc cation is distorted square pyramidal. The three N atoms of the N,N′,N′′-tridentate 8-[2-(di­methyl­amino)­ethyl­amino]­quinoline ligand and one chloride ion constitute a considerably distorted square base. The apical site is occupied by another chloride ion. The distortion from the ideal square-pyramidal geometry is manifested by the N—Zn—N angle of 133.25 (11)°. Like most square-pyramidal metal complexes, the zinc cation is displaced towards the apical chloride ion. In the crystal, mol­ecules are linked by N—H⋯Cl inter­actions. This leads to the formation of chains of mol­ecules parallel to the b-axis direction. International Union of Crystallography 2013-12-04 /pmc/articles/PMC3914037/ /pubmed/24526942 http://dx.doi.org/10.1107/S1600536813029929 Text en © Abdul-Razak H. Al-Sudani 2014 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Metal-Organic Papers
Al-Sudani, Abdul-Razak H.
Di­chlorido­{8-[2-(di­methyl­amino)­ethyl­amino]­quinoline-κ(3) N,N′,N′′}zinc
title Di­chlorido­{8-[2-(di­methyl­amino)­ethyl­amino]­quinoline-κ(3) N,N′,N′′}zinc
title_full Di­chlorido­{8-[2-(di­methyl­amino)­ethyl­amino]­quinoline-κ(3) N,N′,N′′}zinc
title_fullStr Di­chlorido­{8-[2-(di­methyl­amino)­ethyl­amino]­quinoline-κ(3) N,N′,N′′}zinc
title_full_unstemmed Di­chlorido­{8-[2-(di­methyl­amino)­ethyl­amino]­quinoline-κ(3) N,N′,N′′}zinc
title_short Di­chlorido­{8-[2-(di­methyl­amino)­ethyl­amino]­quinoline-κ(3) N,N′,N′′}zinc
title_sort di­chlorido­{8-[2-(di­methyl­amino)­ethyl­amino]­quinoline-κ(3) n,n′,n′′}zinc
topic Metal-Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3914037/
https://www.ncbi.nlm.nih.gov/pubmed/24526942
http://dx.doi.org/10.1107/S1600536813029929
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