Poly[bis­(μ(4)-2,3,5,6-tetra­fluoro­benzene-1,4-di­carboxyl­ato-κ(4) O (1):O (1′):O (4):O (4′))bis­(tetra­hydro­furan-κO)dizinc]

The title compound, [Zn(2)(C(8)F(4)O(4))(2)(C(4)H(8)O)(2)](n), has a three-dimensional metal-organic framework structure. The asymmetric unit consists of two Zn(II) atoms, two tetrahydrofuran ligands, one 2,3,5,6-tetra­fluoro­benzene-1,4-di­carboxyl­ate ligand and two half 2,3,5,6-tetra­fluoro­benze...

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Detalles Bibliográficos
Autores principales: Choi, Sang Beom, Jhon, Young Ho, Ko, Nakeun, Yang, Jin Kuk
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2013
Materias:
Metal-Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3914039/
https://www.ncbi.nlm.nih.gov/pubmed/24526955
http://dx.doi.org/10.1107/S1600536813031887
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author Choi, Sang Beom
Jhon, Young Ho
Ko, Nakeun
Yang, Jin Kuk
author_facet Choi, Sang Beom
Jhon, Young Ho
Ko, Nakeun
Yang, Jin Kuk
author_sort Choi, Sang Beom
collection PubMed
description The title compound, [Zn(2)(C(8)F(4)O(4))(2)(C(4)H(8)O)(2)](n), has a three-dimensional metal-organic framework structure. The asymmetric unit consists of two Zn(II) atoms, two tetrahydrofuran ligands, one 2,3,5,6-tetra­fluoro­benzene-1,4-di­carboxyl­ate ligand and two half 2,3,5,6-tetra­fluoro­benzene-1,4-di­carboxyl­ate ligands, which are completed by inversion symmetry. One Zn(II) atom has a distorted trigonal–bipyramidal coordination geometry, while the other has a distorted octa­hedral geometry. Two independent tetra­hydro­furan ligands are each disordered over two sets of sites with occupancy ratios of 0.48 (4):0.52 (4) and 0.469 (17):0.531 (17).
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spelling pubmed-39140392014-02-13 Poly[bis­(μ(4)-2,3,5,6-tetra­fluoro­benzene-1,4-di­carboxyl­ato-κ(4) O (1):O (1′):O (4):O (4′))bis­(tetra­hydro­furan-κO)dizinc] Choi, Sang Beom Jhon, Young Ho Ko, Nakeun Yang, Jin Kuk Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers The title compound, [Zn(2)(C(8)F(4)O(4))(2)(C(4)H(8)O)(2)](n), has a three-dimensional metal-organic framework structure. The asymmetric unit consists of two Zn(II) atoms, two tetrahydrofuran ligands, one 2,3,5,6-tetra­fluoro­benzene-1,4-di­carboxyl­ate ligand and two half 2,3,5,6-tetra­fluoro­benzene-1,4-di­carboxyl­ate ligands, which are completed by inversion symmetry. One Zn(II) atom has a distorted trigonal–bipyramidal coordination geometry, while the other has a distorted octa­hedral geometry. Two independent tetra­hydro­furan ligands are each disordered over two sets of sites with occupancy ratios of 0.48 (4):0.52 (4) and 0.469 (17):0.531 (17). International Union of Crystallography 2013-12-04 /pmc/articles/PMC3914039/ /pubmed/24526955 http://dx.doi.org/10.1107/S1600536813031887 Text en © Choi et al. 2014 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Metal-Organic Papers
Choi, Sang Beom
Jhon, Young Ho
Ko, Nakeun
Yang, Jin Kuk
Poly[bis­(μ(4)-2,3,5,6-tetra­fluoro­benzene-1,4-di­carboxyl­ato-κ(4) O (1):O (1′):O (4):O (4′))bis­(tetra­hydro­furan-κO)dizinc]
title Poly[bis­(μ(4)-2,3,5,6-tetra­fluoro­benzene-1,4-di­carboxyl­ato-κ(4) O (1):O (1′):O (4):O (4′))bis­(tetra­hydro­furan-κO)dizinc]
title_full Poly[bis­(μ(4)-2,3,5,6-tetra­fluoro­benzene-1,4-di­carboxyl­ato-κ(4) O (1):O (1′):O (4):O (4′))bis­(tetra­hydro­furan-κO)dizinc]
title_fullStr Poly[bis­(μ(4)-2,3,5,6-tetra­fluoro­benzene-1,4-di­carboxyl­ato-κ(4) O (1):O (1′):O (4):O (4′))bis­(tetra­hydro­furan-κO)dizinc]
title_full_unstemmed Poly[bis­(μ(4)-2,3,5,6-tetra­fluoro­benzene-1,4-di­carboxyl­ato-κ(4) O (1):O (1′):O (4):O (4′))bis­(tetra­hydro­furan-κO)dizinc]
title_short Poly[bis­(μ(4)-2,3,5,6-tetra­fluoro­benzene-1,4-di­carboxyl­ato-κ(4) O (1):O (1′):O (4):O (4′))bis­(tetra­hydro­furan-κO)dizinc]
title_sort poly[bis­(μ(4)-2,3,5,6-tetra­fluoro­benzene-1,4-di­carboxyl­ato-κ(4) o (1):o (1′):o (4):o (4′))bis­(tetra­hydro­furan-κo)dizinc]
topic Metal-Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3914039/
https://www.ncbi.nlm.nih.gov/pubmed/24526955
http://dx.doi.org/10.1107/S1600536813031887
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AT yangjinkuk polybism42356tetrafluorobenzene14dicarboxylatok4o1o1o4o4bistetrahydrofurankodizinc

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