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catena-Poly[[diaquabis(4-formylbenzoato-κO (1))copper(II)]-μ-pyrazine-κ(2) N:N′]
In the title polymeric compound, [Cu(C(8)H(5)O(3))(2)(C(4)H(4)N(2))(H(2)O)(2)](n), the Cu(II) atom is located on a twofold rotation axis and has a slightly distorted octahedral coordination sphere. In the equatorial plane, it is coordinated by two carboxylate O atoms of two symmetry-related monode...
Autores principales: | , , , , |
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Formato: | Online Artículo Texto |
Lenguaje: | English |
Publicado: |
International Union of Crystallography
2013
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3914040/ https://www.ncbi.nlm.nih.gov/pubmed/24526956 http://dx.doi.org/10.1107/S1600536813032297 |
Sumario: | In the title polymeric compound, [Cu(C(8)H(5)O(3))(2)(C(4)H(4)N(2))(H(2)O)(2)](n), the Cu(II) atom is located on a twofold rotation axis and has a slightly distorted octahedral coordination sphere. In the equatorial plane, it is coordinated by two carboxylate O atoms of two symmetry-related monodentate formylbenzoate anions and by two N atoms of the bridging pyrazine ligand, which is bisected by the twofold rotation axis. The axial positions are occupied by two O atoms of the coordinating water molecules. In the formylbenzoate anion, the carboxylate group is twisted away from the attached benzene ring by 6.2 (2)°, while the benzene and pyrazine rings are oriented at a dihedral angle of 68.91 (8)°. The pyrazine ligands bridge the Cu(II) cations, forming polymeric chains running along the b-axis direction. Strong intramolecular O—H⋯O hydrogen bonds link the water molecules to the carboxylate O atoms. In the crystal, O—H(water)⋯O(water) hydrogen bonds link adjacent chains into layers parallel to the bc plane. The layers are linked via C—H(pyrazine)⋯O(formyl) hydrogen bonds, forming a three-dimensional network. There are also weak C—H⋯π interactions present. |
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