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catena-Poly[[di­aqua­bis­(4-formyl­benzoato-κO (1))copper(II)]-μ-pyrazine-κ(2) N:N′]

In the title polymeric compound, [Cu(C(8)H(5)O(3))(2)(C(4)H(4)N(2))(H(2)O)(2)](n), the Cu(II) atom is located on a twofold rotation axis and has a slightly distorted octa­hedral coordination sphere. In the equatorial plane, it is coordinated by two carboxyl­ate O atoms of two symmetry-related monode...

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Detalles Bibliográficos
Autores principales: Çelik, Fatih, Dilek, Nefise, Çaylak Delibaş, Nagihan, Necefoğlu, Hacali, Hökelek, Tuncer
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2013
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3914040/
https://www.ncbi.nlm.nih.gov/pubmed/24526956
http://dx.doi.org/10.1107/S1600536813032297
Descripción
Sumario:In the title polymeric compound, [Cu(C(8)H(5)O(3))(2)(C(4)H(4)N(2))(H(2)O)(2)](n), the Cu(II) atom is located on a twofold rotation axis and has a slightly distorted octa­hedral coordination sphere. In the equatorial plane, it is coordinated by two carboxyl­ate O atoms of two symmetry-related monodentate formyl­benzoate anions and by two N atoms of the bridging pyrazine ligand, which is bis­ected by the twofold rotation axis. The axial positions are occupied by two O atoms of the coordinating water mol­ecules. In the formyl­benzoate anion, the carboxyl­ate group is twisted away from the attached benzene ring by 6.2 (2)°, while the benzene and pyrazine rings are oriented at a dihedral angle of 68.91 (8)°. The pyrazine ligands bridge the Cu(II) cations, forming polymeric chains running along the b-axis direction. Strong intra­molecular O—H⋯O hydrogen bonds link the water mol­ecules to the carboxyl­ate O atoms. In the crystal, O—H(water)⋯O(water) hydrogen bonds link adjacent chains into layers parallel to the bc plane. The layers are linked via C—H(pyrazine)⋯O(form­yl) hydrogen bonds, forming a three-dimensional network. There are also weak C—H⋯π inter­actions present.