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catena-Poly[[diaquabis(4-formylbenzoato-κO (1))copper(II)]-μ-pyrazine-κ(2) N:N′]
In the title polymeric compound, [Cu(C(8)H(5)O(3))(2)(C(4)H(4)N(2))(H(2)O)(2)](n), the Cu(II) atom is located on a twofold rotation axis and has a slightly distorted octahedral coordination sphere. In the equatorial plane, it is coordinated by two carboxylate O atoms of two symmetry-related monode...
Autores principales: | , , , , |
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Formato: | Online Artículo Texto |
Lenguaje: | English |
Publicado: |
International Union of Crystallography
2013
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3914040/ https://www.ncbi.nlm.nih.gov/pubmed/24526956 http://dx.doi.org/10.1107/S1600536813032297 |
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author | Çelik, Fatih Dilek, Nefise Çaylak Delibaş, Nagihan Necefoğlu, Hacali Hökelek, Tuncer |
author_facet | Çelik, Fatih Dilek, Nefise Çaylak Delibaş, Nagihan Necefoğlu, Hacali Hökelek, Tuncer |
author_sort | Çelik, Fatih |
collection | PubMed |
description | In the title polymeric compound, [Cu(C(8)H(5)O(3))(2)(C(4)H(4)N(2))(H(2)O)(2)](n), the Cu(II) atom is located on a twofold rotation axis and has a slightly distorted octahedral coordination sphere. In the equatorial plane, it is coordinated by two carboxylate O atoms of two symmetry-related monodentate formylbenzoate anions and by two N atoms of the bridging pyrazine ligand, which is bisected by the twofold rotation axis. The axial positions are occupied by two O atoms of the coordinating water molecules. In the formylbenzoate anion, the carboxylate group is twisted away from the attached benzene ring by 6.2 (2)°, while the benzene and pyrazine rings are oriented at a dihedral angle of 68.91 (8)°. The pyrazine ligands bridge the Cu(II) cations, forming polymeric chains running along the b-axis direction. Strong intramolecular O—H⋯O hydrogen bonds link the water molecules to the carboxylate O atoms. In the crystal, O—H(water)⋯O(water) hydrogen bonds link adjacent chains into layers parallel to the bc plane. The layers are linked via C—H(pyrazine)⋯O(formyl) hydrogen bonds, forming a three-dimensional network. There are also weak C—H⋯π interactions present. |
format | Online Article Text |
id | pubmed-3914040 |
institution | National Center for Biotechnology Information |
language | English |
publishDate | 2013 |
publisher | International Union of Crystallography |
record_format | MEDLINE/PubMed |
spelling | pubmed-39140402014-02-13 catena-Poly[[diaquabis(4-formylbenzoato-κO (1))copper(II)]-μ-pyrazine-κ(2) N:N′] Çelik, Fatih Dilek, Nefise Çaylak Delibaş, Nagihan Necefoğlu, Hacali Hökelek, Tuncer Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers In the title polymeric compound, [Cu(C(8)H(5)O(3))(2)(C(4)H(4)N(2))(H(2)O)(2)](n), the Cu(II) atom is located on a twofold rotation axis and has a slightly distorted octahedral coordination sphere. In the equatorial plane, it is coordinated by two carboxylate O atoms of two symmetry-related monodentate formylbenzoate anions and by two N atoms of the bridging pyrazine ligand, which is bisected by the twofold rotation axis. The axial positions are occupied by two O atoms of the coordinating water molecules. In the formylbenzoate anion, the carboxylate group is twisted away from the attached benzene ring by 6.2 (2)°, while the benzene and pyrazine rings are oriented at a dihedral angle of 68.91 (8)°. The pyrazine ligands bridge the Cu(II) cations, forming polymeric chains running along the b-axis direction. Strong intramolecular O—H⋯O hydrogen bonds link the water molecules to the carboxylate O atoms. In the crystal, O—H(water)⋯O(water) hydrogen bonds link adjacent chains into layers parallel to the bc plane. The layers are linked via C—H(pyrazine)⋯O(formyl) hydrogen bonds, forming a three-dimensional network. There are also weak C—H⋯π interactions present. International Union of Crystallography 2013-12-07 /pmc/articles/PMC3914040/ /pubmed/24526956 http://dx.doi.org/10.1107/S1600536813032297 Text en © Çelik et al. 2014 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited. |
spellingShingle | Metal-Organic Papers Çelik, Fatih Dilek, Nefise Çaylak Delibaş, Nagihan Necefoğlu, Hacali Hökelek, Tuncer catena-Poly[[diaquabis(4-formylbenzoato-κO (1))copper(II)]-μ-pyrazine-κ(2) N:N′] |
title |
catena-Poly[[diaquabis(4-formylbenzoato-κO
(1))copper(II)]-μ-pyrazine-κ(2)
N:N′] |
title_full |
catena-Poly[[diaquabis(4-formylbenzoato-κO
(1))copper(II)]-μ-pyrazine-κ(2)
N:N′] |
title_fullStr |
catena-Poly[[diaquabis(4-formylbenzoato-κO
(1))copper(II)]-μ-pyrazine-κ(2)
N:N′] |
title_full_unstemmed |
catena-Poly[[diaquabis(4-formylbenzoato-κO
(1))copper(II)]-μ-pyrazine-κ(2)
N:N′] |
title_short |
catena-Poly[[diaquabis(4-formylbenzoato-κO
(1))copper(II)]-μ-pyrazine-κ(2)
N:N′] |
title_sort | catena-poly[[diaquabis(4-formylbenzoato-κo
(1))copper(ii)]-μ-pyrazine-κ(2)
n:n′] |
topic | Metal-Organic Papers |
url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3914040/ https://www.ncbi.nlm.nih.gov/pubmed/24526956 http://dx.doi.org/10.1107/S1600536813032297 |
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