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catena-Poly[[di­aqua­bis­(4-formyl­benzoato-κO (1))copper(II)]-μ-pyrazine-κ(2) N:N′]

In the title polymeric compound, [Cu(C(8)H(5)O(3))(2)(C(4)H(4)N(2))(H(2)O)(2)](n), the Cu(II) atom is located on a twofold rotation axis and has a slightly distorted octa­hedral coordination sphere. In the equatorial plane, it is coordinated by two carboxyl­ate O atoms of two symmetry-related monode...

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Autores principales: Çelik, Fatih, Dilek, Nefise, Çaylak Delibaş, Nagihan, Necefoğlu, Hacali, Hökelek, Tuncer
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2013
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3914040/
https://www.ncbi.nlm.nih.gov/pubmed/24526956
http://dx.doi.org/10.1107/S1600536813032297
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author Çelik, Fatih
Dilek, Nefise
Çaylak Delibaş, Nagihan
Necefoğlu, Hacali
Hökelek, Tuncer
author_facet Çelik, Fatih
Dilek, Nefise
Çaylak Delibaş, Nagihan
Necefoğlu, Hacali
Hökelek, Tuncer
author_sort Çelik, Fatih
collection PubMed
description In the title polymeric compound, [Cu(C(8)H(5)O(3))(2)(C(4)H(4)N(2))(H(2)O)(2)](n), the Cu(II) atom is located on a twofold rotation axis and has a slightly distorted octa­hedral coordination sphere. In the equatorial plane, it is coordinated by two carboxyl­ate O atoms of two symmetry-related monodentate formyl­benzoate anions and by two N atoms of the bridging pyrazine ligand, which is bis­ected by the twofold rotation axis. The axial positions are occupied by two O atoms of the coordinating water mol­ecules. In the formyl­benzoate anion, the carboxyl­ate group is twisted away from the attached benzene ring by 6.2 (2)°, while the benzene and pyrazine rings are oriented at a dihedral angle of 68.91 (8)°. The pyrazine ligands bridge the Cu(II) cations, forming polymeric chains running along the b-axis direction. Strong intra­molecular O—H⋯O hydrogen bonds link the water mol­ecules to the carboxyl­ate O atoms. In the crystal, O—H(water)⋯O(water) hydrogen bonds link adjacent chains into layers parallel to the bc plane. The layers are linked via C—H(pyrazine)⋯O(form­yl) hydrogen bonds, forming a three-dimensional network. There are also weak C—H⋯π inter­actions present.
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spelling pubmed-39140402014-02-13 catena-Poly[[di­aqua­bis­(4-formyl­benzoato-κO (1))copper(II)]-μ-pyrazine-κ(2) N:N′] Çelik, Fatih Dilek, Nefise Çaylak Delibaş, Nagihan Necefoğlu, Hacali Hökelek, Tuncer Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers In the title polymeric compound, [Cu(C(8)H(5)O(3))(2)(C(4)H(4)N(2))(H(2)O)(2)](n), the Cu(II) atom is located on a twofold rotation axis and has a slightly distorted octa­hedral coordination sphere. In the equatorial plane, it is coordinated by two carboxyl­ate O atoms of two symmetry-related monodentate formyl­benzoate anions and by two N atoms of the bridging pyrazine ligand, which is bis­ected by the twofold rotation axis. The axial positions are occupied by two O atoms of the coordinating water mol­ecules. In the formyl­benzoate anion, the carboxyl­ate group is twisted away from the attached benzene ring by 6.2 (2)°, while the benzene and pyrazine rings are oriented at a dihedral angle of 68.91 (8)°. The pyrazine ligands bridge the Cu(II) cations, forming polymeric chains running along the b-axis direction. Strong intra­molecular O—H⋯O hydrogen bonds link the water mol­ecules to the carboxyl­ate O atoms. In the crystal, O—H(water)⋯O(water) hydrogen bonds link adjacent chains into layers parallel to the bc plane. The layers are linked via C—H(pyrazine)⋯O(form­yl) hydrogen bonds, forming a three-dimensional network. There are also weak C—H⋯π inter­actions present. International Union of Crystallography 2013-12-07 /pmc/articles/PMC3914040/ /pubmed/24526956 http://dx.doi.org/10.1107/S1600536813032297 Text en © Çelik et al. 2014 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Metal-Organic Papers
Çelik, Fatih
Dilek, Nefise
Çaylak Delibaş, Nagihan
Necefoğlu, Hacali
Hökelek, Tuncer
catena-Poly[[di­aqua­bis­(4-formyl­benzoato-κO (1))copper(II)]-μ-pyrazine-κ(2) N:N′]
title catena-Poly[[di­aqua­bis­(4-formyl­benzoato-κO (1))copper(II)]-μ-pyrazine-κ(2) N:N′]
title_full catena-Poly[[di­aqua­bis­(4-formyl­benzoato-κO (1))copper(II)]-μ-pyrazine-κ(2) N:N′]
title_fullStr catena-Poly[[di­aqua­bis­(4-formyl­benzoato-κO (1))copper(II)]-μ-pyrazine-κ(2) N:N′]
title_full_unstemmed catena-Poly[[di­aqua­bis­(4-formyl­benzoato-κO (1))copper(II)]-μ-pyrazine-κ(2) N:N′]
title_short catena-Poly[[di­aqua­bis­(4-formyl­benzoato-κO (1))copper(II)]-μ-pyrazine-κ(2) N:N′]
title_sort catena-poly[[di­aqua­bis­(4-formyl­benzoato-κo (1))copper(ii)]-μ-pyrazine-κ(2) n:n′]
topic Metal-Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3914040/
https://www.ncbi.nlm.nih.gov/pubmed/24526956
http://dx.doi.org/10.1107/S1600536813032297
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