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Bis(4-aminopyridinium) hexaaquanickel(II) bis(sulfate)
In the title compound, (C(5)H(7)N(2))(2)[Ni(H(2)O)(6)](SO(4))(2), the Ni(II) cation is located on an inversion centre and is coordinated by six aqua ligands in a slightly distorted octahedral coordination environment. The [Ni(H(2)O)(6)](2+) ions are connected through an extensive network of O—H⋯O h...
Autores principales: | , , |
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Formato: | Online Artículo Texto |
Lenguaje: | English |
Publicado: |
International Union of Crystallography
2013
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3914041/ https://www.ncbi.nlm.nih.gov/pubmed/24526957 http://dx.doi.org/10.1107/S1600536813032558 |
Sumario: | In the title compound, (C(5)H(7)N(2))(2)[Ni(H(2)O)(6)](SO(4))(2), the Ni(II) cation is located on an inversion centre and is coordinated by six aqua ligands in a slightly distorted octahedral coordination environment. The [Ni(H(2)O)(6)](2+) ions are connected through an extensive network of O—H⋯O hydrogen bonds to sulfate anions, leading to the formation of layers parallel to (001). The 4-aminopyridinium cations are located between these layers and are connected to the anionic framework by N—H⋯O hydrogen bonds. Weak π–π interactions between the pyridine rings, with a centroid–centroid distance of 3.754 (9) Å, provide additional stability to the crystal packing. |
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